The bismuth in 0.7405 g of an alloy was precipitated as BIOCI and separated from the solution by filtration. The washed precipitate was dissolved in nitric acid and treated with 10.00 mL of 0.1498 M AgNO3, causing the precipitation of AgCl. The excess AgNO3 required 12.92 mL of 0.1008 M KSCN for titration. Calculate the %Bi in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
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Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
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Problem 17.35QAP
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The bismuth in 0.7405 g of an alloy was precipitated as BIOCI and separated from the solution by filtration. The washed precipitate was dissolved in nitric acid and treated with 10.00 mL of 0.1498 M AgNO3, causing the precipitation of AgCl. The excess AgNO3 required 12.92 mL of 0.1008 M KSCN for titration. Calculate the %Bi in the sample. 

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