This data below applies to questions 19 - 23. A 22.34 g sample of chromium ore consisting of impure chromium oxide, Cr203, was analyzed by treating it with hydrogen peroxide, which converted all the chromium oxide into chromate ion (CrO4²-): 2 Cr203 (s) + 3 H2O2 (aq) + 4 OH → CrO42- (aq) + 5 H20 (1) O.The solution containing the chromate ion from the sample was diluted to a volume of 0.500 L. A Beer's law plot made with a standard solution of CrO,²-, using a cell with b = 1.00 cm was found to have a slope of 2.81 L/mol (and a negligible intercept); the solution made from the ore sample showed an absorbance of 1.618 when measured in an identical cell. Using these data, calculate the answers to questions 16 - 20. (You may want to work the answers out on paper before entering them. If you use scientific notation, enter it in "calculator" format, i. e. "1.234e-5")

This data below applies to questions 19 - 23. A 22.34 g sample of chromium ore consisting of impure chromium oxide, Cr203, was analyzed by treating it with hydrogen peroxide, which converted all the chromium oxide into chromate ion (CrO4²-): 2 Cr203 (s) + 3 H2O2 (aq) + 4 OH → CrO42- (aq) + 5 H20 (1) O.The solution containing the chromate ion from the sample was diluted to a volume of 0.500 L. A Beer's law plot made with a standard solution of CrO,²-, using a cell with b = 1.00 cm was found to have a slope of 2.81 L/mol (and a negligible intercept); the solution made from the ore sample showed an absorbance of 1.618 when measured in an identical cell. Using these data, calculate the answers to questions 16 - 20. (You may want to work the answers out on paper before entering them. If you use scientific notation, enter it in "calculator" format, i. e. "1.234e-5")

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter15: Solutions

Section: Chapter Questions

Problem 143CP: When organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of...

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Xenon trioxide, XeO3, reacts with aqueous base to form the xenate anion, HXeO4. This ion reacts further with OH to form the perxenate anion, XeO64, in the following reaction: 2HXeO4(aq)+2OH(aq)XeO64(aq)+Xe(g)+O2(g)+2H2O(l) Identify the elements that are oxidized and reduced in this reaction. You will note that the equation is balanced with respect to the number of atoms on either side. Verify that the redox part of this equation is also balanced, that is, that the extents of oxidation and reduction are also equal.
Magnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?
Triiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?
Azurite is a copper-containing mineral that often forms beautiful crystals. Its formula is Cu3(CO3)2(OH)2. Write balanced equation for the reaction of this mineral with hydrochloric acid.
The metals industry was a major source of air pollution years ago. One common process involved roasting metal sulfides in the air 2 PbS(s) + 3 O2(g) 2 PbO(s) + 2 SO2(g) If 2.50 mol of PbS is heated in air, what amount of O2 is required for complete reaction? What amounts of PbO and SO2 are expected?
A 1.345-g sample of a compound of barium and oxygen was dissolved in hydrochloric acid to give a solution of barium ion, which was then precipitated with an excess of potassium chromate to give 2.012 g of barium chromate, BaCrO4. What is the formula of the compound?
The blood alcohol (C2H5OH) level can be determined by titrating a sample of blood plasma with an acidic potassium di-chromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72) is orange in solution, and the Cr3+ ion is green. The balanced equations is 16H+(aq) + 2Cr2O72(aq) + C2H5OH(aq) 4Cr4+(aq) + 2CO2(g) + 11H2O(l) This reaction is an oxidationreduction reaction. What species is reduced, and what species is oxidized? How many electrons are transferred in the balanced equation above?
4.28 One of the steps in the manufacture of nitric acid is the oxidation of ammonia shown in this equation: 4NH3(g)+5O2(g)4NO(g)+6H2O(g) If 43.0 kg of NH3 reacts with 35.4 kg of O2, what mass of NO forms?
When organic compounds containing sulfur are burned, sulfur dioxide is produced. The amount of SO2formed can be determined by the reaction with hydrogen peroxide: H2O2(aq)+SO2(g)H2SO4(aq) The resulting sulfuric acid is then titrated with a standard NaOH solution. A 1 .302-g sample of coal is burned, and the SO2is collected in a solution of hydrogen peroxide. It took 28.44 mL of a 0.1000 M NaOH solution to titrate the resulting sulfuric acid. Calculate the mass percent of sulfur in the coal sample. Sulfuric acid has two acidic hydrogens.
Complete the missing information in the following skeletion equation and balance the chemical equation: NaOH(aq)+3NaCl(aq)+Al(OH)3(aq)
Chlorisondamine chloride (C14H20Cl6N2) is a drug used in the treatment of hypertension. A 1.28-g sample of a medication containing the drug was treated to destroy the organic material and to release all the chlorine as chloride ion. When the filtered solution containing chloride ion was treated with an excess of silver nitrate, 0.104 g silver chloride was recovered. Calculate the mass percent of chlorisondamine chloride in the medication, assuming the drug is the only source of chloride.
Write the net ionic equation for the reaction, if any, that occurs on mixing (a) solutions of sodium hydroxide and magnesium chloride. (b) solutions of sodium nitrate and magnesium bromide. (c) magnesium metal and a solution of hydrochloric acid to produce magnesium chloride and hydrogen. Magnesium metal reacting with HCl.