(To answer the questions, type the numeral (e.g. 1) in the boxes provided below) H,C H,C C-CH2 Br, light H3C- CH 3 product(s) CH3 Compound A a)Compound A has tertiary carbon(s) b)Compound A has chiral centre(s) c)How many alkyl halide products can possibly be formed if compound A undergoes free radical monobromination? (only count constitutional isomers) Answer = Alkyl halide B is shown below. H H,C H3C C-CH, C-CH 2-CH CH 2 CH 3 Br Compound B d)Select the corresponding number to indicate whether alkyl halide B is a possible product of the free radical monohromination of compound A

(To answer the questions, type the numeral (e.g. 1) in the boxes provided below) H,C H,C C-CH2 Br, light H3C- CH 3 product(s) CH3 Compound A a)Compound A has tertiary carbon(s) b)Compound A has chiral centre(s) c)How many alkyl halide products can possibly be formed if compound A undergoes free radical monobromination? (only count constitutional isomers) Answer = Alkyl halide B is shown below. H H,C H3C C-CH, C-CH 2-CH CH 2 CH 3 Br Compound B d)Select the corresponding number to indicate whether alkyl halide B is a possible product of the free radical monohromination of compound A

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter19: Eas: Electrophilic Aromatic Substitution

Section: Chapter Questions

Problem 7E: When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2)...

See similar textbooks

Similar questions

3) Draw the structures of the major organic product(s) for the following reactions. HI in CH₂Cl₂ 3 excess Cl₂ in H₂O H₂SO4 in H₂O (Two products) Br-Cl in THF 1) BH3 2) alkaline H₂O₂ OSO4 + HOOH
a) How many different molecules containing one double bond can be used to synthesize 4-methyl-4-heptanol (as the major product) via acid catalyzed hydration with H2SO4 and H2O? Draw them all below. b) Are any of the structures in part (a) trisubstituted alkenes? If so, redraw it/them below.
Draw the alkene that would react with the reagent given to account for the product formed. ? + + H₂O **** H₂S04 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. CH3 CH3 CHCCH3 | | OH CH3 +1
Please draw out all missing parts of the reaction like as in reagents, products starting materials) H3C CH3 H30", A H,CH,Co OCH,CH;
[References] Draw the alkene structure that produced the following compounds in a ozonolysis reaction as specified. 1. O3 C7H12 2. (CH3)2S
The reagents below (A-E) are used for the following questions. A H D Br PPh3 :0: H. e B :0: PPh3 (+) E H Which reagents are Wittig reagents? [Select] H Br. :0: Which Wittig reagent would yield a Z alkene when reacted when an aldehyde/ketone? [Select] C Recall the definition/structure of a Wittig reagent. Which reagents could be used to make a Wittig reagent? [Select] H
11) a) How many different molecules containing one double bond can be used to synthesize 4-methyl-4-heptanol (as the major product) via acid catalyzed hydration with H2SOe and H20? Draw them all below. b) Are any of the structures in part (a) trisubstituted alkenes? If so, redraw it/them below. c) Label (if possible) the structure(s) in part (b) as either Z or E double bond isomers. Bonus Question: ) Recently, the Gademann research group from the University of Zurich, completed the synthesis of (+)-Peyssonnosol, a complex natural product (shown below on the left) which contains seven stereocenters. Briefly describe what the "(t)" symbol in front of the synthesized natural product name means. Me., Me, Me Me HO. Me Me Synthesized ()-Peyssonnosol Starting Materials Used inSynthesis
When toluene is treated with sulfuric and nitric acids under special conditions, three nitro (NO2) groups are substituted for hydrogens at the 2, 4 and 6 positions on the ring (the next section discusses why the 2, 4, and 6 positions are substituted). The product is a highly explosive substance called 2,4,6-trinitrotoluene. This subastance is commonly known by a three letter name. What is it?
R'R°CHOH-CR'R* R'R?C=CR*R* What should orientation of each substituent in reactant to convert it into product alkene? What is importance of their specific orientation?
Draw the organic product of the following reaction. CH3 m-CICgH,CO;H • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, just draw one stereoisomer. • If more than one product is possible, only draw the major product. opy aste
Which of the products is correct for this reaction listed? Z-alkene, E-alkene, both, none?
МЕСНANISMS 1,2-epoxy-1-methylcyclopentane undergoes both acid-catalyzed and base-catalyzed opening of the epoxide ring to form two different products. > Using ethanol as the solvent and an appropriate acid, show the steps in the acid catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). > Using ethanol as the solvent and an appropriate base, show the steps in the base- catalyzed mechanism, writing structures for all products of the steps. Circle the major product(s). 1,2-epoxy-1-methylcyclopentane CH3