Use the image below to answer the following three questions. Note: Subscripts are not shown in answer choices, ex: H2 should be H2, NH3 should be NH3. Product A Product B Product C a. The reagents that would selectively yield Product A are [ Select ] b. The reagents that would selectively yield Product B are [ Select ] C. The reagents that would selectively yield Product C are Select
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- Use the image below to answer the following three questions. Note: Subscripts are not shown in answer choices, ex: H2 should be H2, NH3 should be NH3. Product A Product B Product C a. The reagents that would selectively yield ProductA are [ Select] b. The reagents that would selectively yield Product B are [Select] c. The reagents that would selectively yield Product Care [Select]4. Circle the electrophilic and nucleophilic atoms in each substitution reaction below. Provide the neutral organic product; where a stereocenter is created, use a wavy bond to indicate a mixture of configurations or wedges/dashes for stereospecific reactions. Also, provide the dominant reaction mechanism (Sn2 or SN1) somewhere in each box. A. Br NaSEt DMF В. ELOH C. .SO2NHNA Cl + D. NaH Br- HO, DMF6. Multi Step Synthesis. Propose a synthetic route from the reactant to the product using any reagents you need. Nalt LINH4
- Draw the major product of this reaction. Ignore inorganic byproducts. 0 1. CrO3, H₂SO4 2. Neutralizing work-up H .2. Но ... H-O Draw the major product of this reaction. Explain your reasoning. Br₂, H₂O EtOH 1. Me₂ BuSi-CI, imidazole 2.9-BBN-H (like BH3) 3. H₂O₂, NaOH OTMS excess HBrThis reaction is an example of conjugate addition of a nucleophile to an a,ẞ-unsaturated carbonyl. O CH3CH2CH2CH=CHCSCOA H₂O OH CH3CH2CH2CHCH2CSCOA Draw the two resonance structures of the enolate anion intermediate for this reaction. • Draw an R1 group in place of COA. The R group tool is located in the charges and lone pairs drop-down menu. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate resonance structures using the symbol from the drop-down menu. ->> 90-87 O + ? ChemDoodle >
- 1. Propose a synthetic route from the starting material to the product. Show each individual reaction step and all intermediate products. Assume acidic workups occur if needed. Starting Material Product a. b. Hint: Number the carbons in your starting material and your product. Starting Material Product a-an c. Hint: Pay attention to stereochemistry. Starting Material Product 45. Using curved arrows please give the mechanism of this reaction, including any regioselectivity or stereoselectivity. P. HBr } DCM BrFor the energy diagram below, which of the statements are true for transition state for formation of B I. has lower activation energy than TS for D II. looks like compound A III. looks like compound C IV. is the fastest step of the reaction E, komol A O II OI B C E Reaction rate ~ [substrate ] x [reagent] Reaction progress
- Add curved arrow(s) to draw step 2 of the mechanism. Modify the given drawing of the product as needed to show the intermediate that is formed in this step. H. C N. II P. H. Clo. CI Br HO. Ź + I +† + +1 ****ited Draw both resonance structures of the most stable carbocation intermediate in the reaction shown. od m... • You do not have to consider stereochemistry. . Do not include anionic counter-ions, e.g., I', in your answer. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom Separate resonance structures using the → symbol from the drop-down menu. ● CH4 + ? HBrComplete each of the following statements below using the figure below. NaOH a. In the above reaction, [Select ] is the nucleophile. b. In the above reaction, [Select ] is the electrophile. C. In the above reaction, [Select ] is the leaving group. C. The above reaction should proceed via an [ Select ] mechanism.