Use the information given in the following paragraph and energy diagram to answer questions 5-10. The mechanism for the reaction 2A D is illustrated in the following energy diagram where the X- axis is "reaction progress" and the Y-axis is "enthalpy". A is the reactant and D is the product. The reaction has a rate constant of 5.0x102² Mr¹ sec" when no catalyst is present. The equilibrium constant for the overall reaction at 25°C is K [D] = -=1.1×102. [A]² R D 9. You proposed the following mechanism for the overall reaction 2A D based on the energy diagram Step 1. A B (slow), with forward rate constant, k₂ (fast equilibrium), with forward rate constant, k₁, reverse rate constant k.] and equilibrium constant, K₁. Step 2. B 2C Step 3. A+2C D (fast), with forward rate constant, k3 Your classmate pointed out that your mechanism is incorrect. Why is your mechanism incorrect? a. Your mechanism does not incorporate the use of a catalyst b. Your mechanism is not consistent with the experimental rate law c. Your mechanism does not add up to give the overall reaction d. The rate law for your mechanism does not contain all the rate constants in the mechanism

Chemistry
9th Edition
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Steven S. Zumdahl
Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 5ALQ: Consider the following statements: In general, the rate of a chemical reaction increases a bit at...
icon
Related questions
Question
Use the information given in the following paragraph and energy diagram to answer questions 5-10.
The mechanism for the reaction 2A D is illustrated in the following energy diagram where the X-
axis is "reaction progress" and the Y-axis is "enthalpy". A is the reactant and D is the product. The
reaction has a rate constant of 5.0x102² Mr¹ sec" when no catalyst is present. The equilibrium constant
for the overall reaction at 25°C is K
[D]
=
-=1.1×102.
[A]²
R
D
9. You proposed the following mechanism for the overall reaction 2A D based on the energy
diagram
Step 1. A B
(slow), with forward rate constant, k₂
(fast equilibrium), with forward rate constant, k₁, reverse rate constant k.] and
equilibrium constant, K₁.
Step 2. B 2C
Step 3. A+2C
D
(fast), with forward rate constant, k3
Your classmate pointed out that your mechanism is incorrect. Why is your mechanism incorrect?
a. Your mechanism does not incorporate the use of a catalyst
b. Your mechanism is not consistent with the experimental rate law
c. Your mechanism does not add up to give the overall reaction
d. The rate law for your mechanism does not contain all the rate constants in the mechanism
Transcribed Image Text:Use the information given in the following paragraph and energy diagram to answer questions 5-10. The mechanism for the reaction 2A D is illustrated in the following energy diagram where the X- axis is "reaction progress" and the Y-axis is "enthalpy". A is the reactant and D is the product. The reaction has a rate constant of 5.0x102² Mr¹ sec" when no catalyst is present. The equilibrium constant for the overall reaction at 25°C is K [D] = -=1.1×102. [A]² R D 9. You proposed the following mechanism for the overall reaction 2A D based on the energy diagram Step 1. A B (slow), with forward rate constant, k₂ (fast equilibrium), with forward rate constant, k₁, reverse rate constant k.] and equilibrium constant, K₁. Step 2. B 2C Step 3. A+2C D (fast), with forward rate constant, k3 Your classmate pointed out that your mechanism is incorrect. Why is your mechanism incorrect? a. Your mechanism does not incorporate the use of a catalyst b. Your mechanism is not consistent with the experimental rate law c. Your mechanism does not add up to give the overall reaction d. The rate law for your mechanism does not contain all the rate constants in the mechanism
AI-Generated Solution
AI-generated content may present inaccurate or offensive content that does not represent bartleby’s views.
steps

Unlock instant AI solutions

Tap the button
to generate a solution

Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781133611097
Author:
Steven S. Zumdahl
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
Chemistry
ISBN:
9781337399425
Author:
Steven S. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Introductory Chemistry: An Active Learning Approa…
Introductory Chemistry: An Active Learning Approa…
Chemistry
ISBN:
9781305079250
Author:
Mark S. Cracolice, Ed Peters
Publisher:
Cengage Learning
Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:
9781285869759
Author:
Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:
Cengage Learning
Introductory Chemistry For Today
Introductory Chemistry For Today
Chemistry
ISBN:
9781285644561
Author:
Seager
Publisher:
Cengage