Use the information given in the following paragraph and energy diagram to answer questions 5-10. The mechanism for the reaction 2A D is illustrated in the following energy diagram where the X- axis is "reaction progress" and the Y-axis is "enthalpy". A is the reactant and D is the product. The reaction has a rate constant of 5.0x102² Mr¹ sec" when no catalyst is present. The equilibrium constant for the overall reaction at 25°C is K [D] = -=1.1×102. [A]² R D 9. You proposed the following mechanism for the overall reaction 2A D based on the energy diagram Step 1. A B (slow), with forward rate constant, k₂ (fast equilibrium), with forward rate constant, k₁, reverse rate constant k.] and equilibrium constant, K₁. Step 2. B 2C Step 3. A+2C D (fast), with forward rate constant, k3 Your classmate pointed out that your mechanism is incorrect. Why is your mechanism incorrect? a. Your mechanism does not incorporate the use of a catalyst b. Your mechanism is not consistent with the experimental rate law c. Your mechanism does not add up to give the overall reaction d. The rate law for your mechanism does not contain all the rate constants in the mechanism
Use the information given in the following paragraph and energy diagram to answer questions 5-10. The mechanism for the reaction 2A D is illustrated in the following energy diagram where the X- axis is "reaction progress" and the Y-axis is "enthalpy". A is the reactant and D is the product. The reaction has a rate constant of 5.0x102² Mr¹ sec" when no catalyst is present. The equilibrium constant for the overall reaction at 25°C is K [D] = -=1.1×102. [A]² R D 9. You proposed the following mechanism for the overall reaction 2A D based on the energy diagram Step 1. A B (slow), with forward rate constant, k₂ (fast equilibrium), with forward rate constant, k₁, reverse rate constant k.] and equilibrium constant, K₁. Step 2. B 2C Step 3. A+2C D (fast), with forward rate constant, k3 Your classmate pointed out that your mechanism is incorrect. Why is your mechanism incorrect? a. Your mechanism does not incorporate the use of a catalyst b. Your mechanism is not consistent with the experimental rate law c. Your mechanism does not add up to give the overall reaction d. The rate law for your mechanism does not contain all the rate constants in the mechanism
Chapter12: Chemical Kinetics
Section: Chapter Questions
Problem 5ALQ: Consider the following statements: In general, the rate of a chemical reaction increases a bit at...
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