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- 6. Complete reaction scheme below indicating reagents, catalysts and conditions, and side product trigil bezinslog si6101fon 290b 1l (b Senines levirba 6 gaubong nasamots gniwollot ads to doinW 01 sniowl (6 CH3 40 CH3 Scansgowi (d Ege nodie) ( nsgyxo (b NO₂ 19m02 2i gniwollet sits to mainW II HOowing reactions proceeds via an SN1 or SN2 of the reaction: (b) S2 pro85 39 Br tort atubong auonsV HMPAnoitutitaduaPt + H2 он CH;CHCH, CH; What starting reactant is necessary to complete the reaction above? 2CH;C-H CH,CH, CCH; 2CH;C-H CH,CH, CHCH; Ó-CH;
- Draw the predicted major products of the following reactions. Ph OHC., (PhP);RhCI PHCN, A H,CCH, Grubbs I, CH,OCl, Rh(CO),CI CO R-0 B(OH)2 Pd(OAc)2 K3PO4 Pd(OAc)2 K3PO4OMe O OMe mechanism requires PdCl₂ (cat) A CUCI, O₂ H₂OWhich products are most likely to form in this reaction? NH2 H2N NaNH2 NH2 liq. NH3 II O1, II & II O II & II O1& || OI & II
- 102. The major products A and B in the following reaction sequence are CHO Br Br (i) PPh3 (ii) NaH (A) NaH OH (B)Chemistry HO -OEt HCI (catalytic) H₂O + EtOH Draw the arc arrow mechanism. Include all relevant free electron pairs, arc arrows, formal charges, structures of intermediates and by-products. Hint: the reaction starts with the protonation of alcoholHow many acid-base steps occur in this mechanism? :OH fö OH ₂ H CI: -H₂O (C5H12O) (CsH3O*) :CI: :CI:- yox (C5H1*) (C5H₁1CI)
- Predict the major product of the following reaction. (CH3)3C-OOH LOH TI[OCH(CH3)214 (-)-DET Dom -OH 11 OH Io ||| Ø OH IV7В. (2 Draw the structure of the product, substrate or condition in the following reactions (should clearly indicate the stereochemistry). (а) OH (b) OsO vaHSO3 (c) 1) (sia)2 BH 2) NaOH/H,O2 H20 (d) HBr (2 equiv) Br, Br Hint: This is the only product formed (e) Br Br2 H20 OH (f)3. For questions "A"- "C", complete the following reaction schemes (no mechanisms required). Show all reagents used in the order of application. th A) 6 B) ||| Ins HO HO