What is meant when it says under the nutrition facts that one serving contains 500 calories? Is it equivalent to the enthalpy of combustion of the food?  Explain.

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Problem 129CP: A piece of chocolate cake contains about 400 calories. A nutritional calorie is equal to 1000...
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What is meant when it says under the nutrition facts that one serving
contains 500 calories? Is it equivalent to the enthalpy of combustion of the food? 
Explain.

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