What set of ketone (1) and aldehyde (2) will provide the same alcohol product (3) when submitted to the reaction conditions shown? 1. LIAIH4 (1)- 2. H20 Он 1. MgBr (3) (2) 2. H20 (A) (1) (2) (В) (1) (C) (1) (2) 4. (D) (1) (2)

What set of ketone (1) and aldehyde (2) will provide the same alcohol product (3) when submitted to the reaction conditions shown? 1. LIAIH4 (1)- 2. H20 Он 1. MgBr (3) (2) 2. H20 (A) (1) (2) (В) (1) (C) (1) (2) 4. (D) (1) (2)

Macroscale and Microscale Organic Experiments

7th Edition

ISBN:9781305577190

Author:Kenneth L. Williamson, Katherine M. Masters

Publisher:Kenneth L. Williamson, Katherine M. Masters

Chapter7: Extraction

Section: Chapter Questions

Problem 3Q: The PKa of p-nitrophenol is 7.15. Would you expect this to dissolve in a sodium bicarbonate...

See similar textbooks

Related questions

Q: Explain the salt-like behavior of compound A in under thirty words.

A: About tropylium bromide :

Q: Show the stepwise mechanism for the reaction between methanoyl bromide and methyl amine. Use…

Q: Which or which of the statements given below is correct. I) Maleic anhydride is a carboxylic acid…

A: (I) Maleic anhydride is a carboxylic acid derivative which on reaction with water gives the…

Q: Heating an alcohol with sulfuric acid is a good way to prepare a symmetrical ether such as diethyl…

A: a) Since in case of reacting an alcohol with sulfuric acid, the formed carbocation can be attacked…

Q: B) Cyclopent-2-en-one to 3-oxocyclopentane carboxylic acid C) Cyclopentane to N,N-diethyl…

Q: Tamoxifen is an estrogen receptor modulator that is used in the treatment of breast cancer. Provide…

A: In organic synthesis, suitable reagent converts the reactants into products. Reagents attacks with…

Q: Why is it not advisable to use aqueous hydrochloric acid in a Grignard reaction of a ketone? A) The…

A: Alkyl magnesium halide is known as a Grignard reagent. The general formula of the Grignard reagent…

Q: Devise a synthesis of the ketone hexan-3-one, CH3CH2COCH2CH2CH3, from CH3CH2Br as the only organic…

A: Ethyl bromide react with magnesium in the presence of ether results in the formation of ethyl…

Q: 4. i. Define Hemiacetal, Acetal and Ketal. ii. Give the structure of the product from the reaction…

A: Organic compounds are the compounds which are mainly composed C and H atoms. The branch of chemistry…

Q: The analgesic acetaminophen is synthesized by treating 4-aminophenol with one equivalent of acetic…

A: Given 4-aminophenol + acetic anhydride ----> acetaminophen + additional product

Q: Diazepam, better known as Valium, is a central nervous system (CNS) sedative/ hypnotic. As a…

Q: a. Write the keto-enol tautomerization equation for the following compound OH LOH LOH (a) (b) b.…

Q: Of the following, which represents a logical retrosynthesis for target molecule A? to OH MgBr MgBr…

A: Given Molecule

Q: b) Compound G (C₂H₂O) is a carbonyl compound that will give a negative test towards Tollen's…

A: Given in following question a compound G C4H8O ia carbonyl compound this compound give a negative…

Q: How many carbonyl groups are generated upon treatment of the molecule below with ozone, followed by…

A: We have given the organic compound and find out How many carbonyl groups are generated upon…

Q: From the experimental point of view, highlight why the selenoxide pyrolysis for the dehydration of…

A: The solution of the question is given below:

Q: Q1/Do as required: 1-The role of H2SO4 in Preparation of Nitrobenzene. Explain 2- Preparation of…

A: Nitration of Benzene is carried forward in presence of Sulphuric acid and Nitric acid .

Q: Below is a schematic representation of possible reaction that compound X can undergo.Use the scheme…

A: a. The IUPAC name for Compound X is

Q: 2. THP (tetrahydropyranyl) is a commonly used protecting group for alcohols. As shown below,…

A: Sometimes more than one functional group is present in the compound. When a reagent is added to such…

Q: Consider the following reaction to form compound C. OH H3C cat. Ph H OCN В Ph A a) Indicate the most…

A: More electrophilic centre will react with cat. Cyanide, Because CN- is a nucleophile.

Q: a) Sketch all the steps required for the following synthesis. Compound H b) Write the IUPAC name for…

A: GIVEN:-

Q: 14 1. Suggest a reason why this might be considered a good point for a first disconnection. II.…

A: DCC is used to convert carboxylic acid to amide in the presence of the base. General reaction is…

Q: Provide a stepwise synthesis for benzyl alcohol to sodium benzoate with reagents KMnO4 and NaOH…

Q: When alcohol A is heated with base as shown below, the expected epoxide does not form. Explain why…

Q: When ethyl ether is heated with excess HI for several hours, the only organic product obtained is…

A: Please find below the reaction taking place

Q: Devise a stepwise mechanism for the following reaction, a key step in the synthesis of the…

A: The diester undergoes Dieckmann reaction in the presence of base to form beta-ketoester. The base…

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: Retrosynthesis analysis gives (2) and (3).

Q: c) Scheme 1 shows the retrosynthetic analysis of compound M to the precursors via Functional Group…

A: The given transformation can be done by following reagents A= 1)Mg/Ether, 2) CO2 3) H3O+ B= 1)…

Q: d. Aflatoxin B, hemiacetal racemizes readily in basic solution. OCH3 O: OH Aflatoxin B1 hemiacetal

A: As per the rules, only the first question can be answered. Organic reaction mechanism.

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: There are four chiral centres in the estrone that are marked in the structure below,

Q: In what major form would this diol-aldehyde exist? Н НО ОН НО. НО -ОН НО. B НО Он НО, "ОН D

A: The major form of given diol-aldehyde exist can be drawn as

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: The stereo selective double Heck reaction of arene (1) is highly efficient strategy to prepare the…

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: There are two functional group present in the Estrone. 1. Alcohol 2. Ketone

Q: Explain the following behaviours :(i) Alcohols are more soluble in water than the hydrocarbons of…

A: (i) Alcohols are soluble in water as they form hydrogen bonds with water molecules because of…

Q: Juvabione is produced by fir trees of the genus Abies and is known to inhibit insect reproduction…

Q: Diazepam, better known as Valium, is a central nervous system (CNS) sedative/ hypnotic. As a…

A: The synthesis of diazepam is,

Q: Over the past several decades, chemists have developed a number of synthetic methodologies for the…

A: Compound (2) has the aromatic ring that becomes ring A of estrone. Compound (3) has fused six and…

Q: When trichloroacetaldehyde is dissolved in water, almost all of it is converted to the hydrate.…

A: Trichloroacetaldehyde also called as Chloral is an organic compound with a aldehyde functional…

Q: 15. Outline a synthetic route, with no more than three steps, to accomplish the following…

A: Lactones can be reduced to diols using reducing agents like LiAlH4, LiBH4, DIBAL-H, etc.

Q: from the reaction of elimination of two moles of water from one molecule of ethanediol when treated…

A: An elimination reaction is a form of organic reaction that removes two substituents from a molecule…

Q: 2. Consider the following scheme. NH2 NH2 Reagent A Но ÓH Compound T HO Compound S KOH, NH,NH2…

A: a) The IUPAC name of the given compound T is, 1-amino-1-(4-hydroxy phenyl) propan-2-one b)…

Q: Question attached

A: Synthesis forward reaction and listing reagents and steps for the given reaction,

Q: Please write the corresponding name (only of the products (A, B, C, D and E Compound A is an…

A: for given synthesis the name of compound A , B, C ,D, E in above reaction are given in attach image…

Q: 6) Prepare the following carboxylic acid from Benzene and any other reagent that we have discussed…

Q: 1. Which compound is expected to have a higher melting point, 1-pentanol or 1-pentanal? Explain 2.…

A: 1. Greater is the intermolecular force higher will be the melting point. 1-pentanal is an aldehyde.…

Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

What set of ketone (1) and aldehyde (2) will
provide the same alcohol product (3) when
submitted to the reaction conditions shown?
1. LIAIH
(1)
2. H2O
OH
1. MgBr
(3)
(2)-
2. Нао
(A)
H'
(1)
(2)
(В)
H.
(1)
(2)
(C)
(1)
(2)
(D)
(1)
(2)

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 2 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

1. (a) Which compound would have the highest boiling point? benzophenone toluene acetophenone benzaldehyde (b) Which of the reagents listed below can convert a primary alcohol to an aldehyde? H2CrO4 DMSO, (COCl)2, Et3N AgNO3 KMnO4-, NaOH (c) Oxidation of alcohols involving the use of DMSO and (COCl)2 is also known as which of the following? Jones Tollens Baeyer-Villiger Swern
Give the structure of the principal product(s) when each of the following alcohols reactswith (1) Na2Cr2O7>H2SO4, (2) PCC, (3) DMP, and (4) 1 equiv NaOCl-TEMPO.(a) octan-1-ol (b) octan-3-ol(c) 4-hydroxydecanal
1. (2) Draw the structures of the alcohol expected in each of the following reaction sequesces. 1) Hg(OАc)2, Н20 2) NaBH4 1) Mg, ether Br 2) H. 3) H3O*
2. a) Provide the missing reaction product(s), or conditions to the following reactions. 00 محمد Aco hv DCM, -55 °C NaOH (aq) C11 H1602
Give the structures of the products you would expect when each alcohol reacts with(1) HCl, ZnCl2; (2) HBr; (3) PBr3; (4) P>I2; and (5) SOCl2.(a) butan-1-ol (b) 2-methylbutan-2-ol(c) 2,2-dimethylbutan-1-ol (d) cis-3-methylcyclopentanol
Most alkyl bromide are water-insoluble liquids. But when the following alkyl bromide Awas first isolated, its high melting point of 203oC (solid at room temperature) and its water solubility led its discoverers to comment that it behaves more like a salt (hint: like NaCl). Explain the salt-like behavior of compound A in under thirty words.
Which carbonyl groups in the following reactions would require protection? (a) (b) 1. NaNH, Mg(s) Br -MgBr 2. CH3I (c) (d) ОН NaSCH. NABH4 Ethanol CI H3CS"
Choose the most appropriate reagent(s) to selectively reduce the ketone functional group to an alcohol in the following molecule: (a) NaBH4, then aqueous acid (b) LIAIH, then aqueous acid (c) H2NNH, then KOH, heat (d) H, Pd/C (e) none of (a), (b), (c) or (d) can be used a. b.
4G. 4G 7:41 PM 27 PROBLEM SET – CARBOXYLIC ACIDS 1. Give IUPAC names for the following carboxylic acids: (a) (b) Br (c) CH;CHCH,ČOH CH;CHCH,CH,ČOH CH3CH-CHCH,CH,CH3 (d) H H (e) H C%3C HO,C H3C CH2CH,COH 2. Draw structures corresponding to the following names: (a) 2.3-Dimethylhexanoic acid (b) 4-Methylpentanoic acid
(b) Answer the following questions based on the compounds below. Jawab soalan berikut berdasarkan kepada sebatian di bawah. CI CI A в (i) Which compound has the higher boiling point? Explain. Sebatian manakah mempunyai takat didih yang lebih tinggi? Terangkan. (ii) Draw the SN2 mechanism for the reaction of compound A with sodium hydroxide, NaOH. Lukis mekanisma Sn2 bagi tindak balas antara sebatian A dengan natrium hidroksida, NaOH.
Give the structure of the principal product(s) when each of the following alcohols reacts with (1) Na2Cr2O7/H2SO4, (2) PCC, (3) DMP, and (4) 1 equiv NaOCl-TEMPO. (a) 4-hydroxydecanal (b) 1-methylcyclohexan-1,4-diol
In the reaction between 3-pentanone and 1-propanol in the presence of acid catalyst, the resulting FINAL acetal product has bonded to the four different sides of the central carbon. (NOTE: The numbers in the responses should be subscripted.) -СН2CH3, -СН2CНЗ, -ОСН2СНЗ, and -OCH2CНЗ -(CH2)4CH3, -(CH2)4CH3, -OCH2CH2CH3, and -OCH2CH2CH3 О -н, -СН2СHЗ, -ОСН2СH2CНЗ, and -OCH2CH2CH3 -CН2CH3, -СH2СНЗ, -ОСН2СH2CH3, and -OСH2СH2CH3 -CH2CH3, -CH2CH3, -OCH2CH2CH3, and -OH