Which of the following mixtures is not a buffer solution?  A) 25.0 mL of 0.10 M ammonia plus 20.0 mL of 0.10 M ammonium chloride B) 25.0 mL of 0.10 M ammonia plus 25.0 mL of 0.10 M hydrochloric acid C) 25.0 mL of 0.10 M sodium phosphate plus 20.0 mL of 0.10 M sodium hydrogen phosphate D) 25.0 mL of aqueous 0.10 M sodium phosphate plus 10.0 mL of 0.10 M hydrochloric acid

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Chapter16: Acid-base Equilibria
Section: Chapter Questions
Problem 16.147QP
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Which of the following mixtures is not a buffer solution? 

A) 25.0 mL of 0.10 M ammonia plus 20.0 mL of 0.10 M ammonium chloride

B) 25.0 mL of 0.10 M ammonia plus 25.0 mL of 0.10 M hydrochloric acid

C) 25.0 mL of 0.10 M sodium phosphate plus 20.0 mL of 0.10 M sodium hydrogen phosphate

D) 25.0 mL of aqueous 0.10 M sodium phosphate plus 10.0 mL of 0.10 M hydrochloric acid

Dichloroacetic acid has an ionization constant: Ka = 5.5 × 10-2 . Calculate the [H+ ] and the pH of a 0.100 molar solution of this acid.

A) 7.4 × 10-2 , 1.13 B) 5.2 × 10-2 , 1.29 C) 2.5 × 10-2 , 1.59 D) 3.2 × 10-2 , 1.49

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