The following group of monomers should be ranked from most able to least able to undergo cationic polymerization . Concept Introduction: Cationic polymerization: The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation. The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp 2 carbon bonded to the most h y d r o g e n s .

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Answer 1

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Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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When certain cycloalkenes are used in metathesis reactions, ringopening metathesis polymerization (ROMP) occurs to form a highmolecular- weight polymer, as shown with cyclopentene as the starting material. The reaction is driven to completion by relief of strain in the cycloalkene.What products are formed by ring-opening metathesis polymerization of each alkene?

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

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Answer 5

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 6

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

Answer 7

Chapter 27.4, Problem 7P

(a)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most hydrogens.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The following group of monomers should be ranked from most able to least able to undergo cationic polymerization.

Concept Introduction:

Cationic polymerization:

The polymerization in which an electrophile acts as an initiator and adds to the monomer which leads to the formation of a carbocation.

The initiator widely used is a Lewis acid and in the polymerization the electrophile adds to the sp2 carbon bonded to the most number of hydrogens.

Answer 12

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Answer 14

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Answer 15

Ch. 27.3 - Prob. 1P Ch. 27.3 - Prob. 2P Ch. 27.3 - Prob. 3P Ch. 27.3 - Prob. 4P Ch. 27.3 - Prob. 5P Ch. 27.3 - Prob. 6P Ch. 27.4 - Prob. 7P Ch. 27.5 - Rank the following groups of monomers from most...Ch. 27.5 - Why does methyl methacrylate not undergo cationic...Ch. 27.6 - Prob. 10P

Solution Summary: The author explains that the order of ability in which the given compounds undergo cationic polymerization is based on the stability of carbocation.

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Chapter 27 Solutions