commas separate options Reagent 1list: ch3mgbr h2o, lialh4 h2o, ch3Br, CH3OH reagent 2: PCC, h2cr2o7, nabh4 h2o, lialh4 h2o 3: as shown in image 4: co2 h2o, socl2, hcooh 5: socl2, Hcl, cl2
commas separate options Reagent 1list: ch3mgbr h2o, lialh4 h2o, ch3Br, CH3OH reagent 2: PCC, h2cr2o7, nabh4 h2o, lialh4 h2o 3: as shown in image 4: co2 h2o, socl2, hcooh 5: socl2, Hcl, cl2
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter10: Alcohols
Section10.7: The Pinacol Rearrangement
Problem EQ: Which step in the reaction would you expect to be rate-determining? 1. Vicinal diol to intermediate...
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commas separate options
Reagent 1list: ch3mgbr h2o, lialh4 h2o, ch3Br, CH3OH
reagent 2: PCC, h2cr2o7, nabh4 h2o, lialh4 h2o
3: as shown in image
4: co2 h2o, socl2, hcooh
5: socl2, Hcl, cl2
![OC
Identify reagent(s) 3.
Which carbon is labeled 13C in intermediate 3?
1.
PBr, , pyridine; 2. Mg, ether
O F
1.
Mg, ether 2. PBr3 , pyridine
Which carbon is labeled 1C in intermediate 4?
1.
CH;MGB1 ; 2. H,0
O G
Identify reagent(s) 5.
Which carbon is labeled C in the product?
13
OL](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9f0815ea-ae36-403a-aa7b-ca3546051b89%2Fe03d755d-4119-466d-a780-d5d4ff308740%2Fenxx6uc_processed.jpeg&w=3840&q=75)
Transcribed Image Text:OC
Identify reagent(s) 3.
Which carbon is labeled 13C in intermediate 3?
1.
PBr, , pyridine; 2. Mg, ether
O F
1.
Mg, ether 2. PBr3 , pyridine
Which carbon is labeled 1C in intermediate 4?
1.
CH;MGB1 ; 2. H,0
O G
Identify reagent(s) 5.
Which carbon is labeled C in the product?
13
OL
![13
Propionyl chloride is synthesized from "CO, in a 5-step synthesis. The intermediates are provided for each step. Identify the
missing reagents and identify the position of the labeled carbon atom in each intermediate. The C atom in carbon dioxide is
13
shown in a red color.
H2
reagent 1
CO2
H2
reagent 2
reagent 3
.C
A
H3C
MgBr
H3C
HO.
H;C
intermediate 3
intermediate 1
intermediate 2
reagent 4
H2
H2
.CI
reagent 5
K
H3C
H;C
C.
product: propionyl chloride
intermediate 4
Identify reagent(s) 1.
Which carbon is labeled 13C in intermediate 1?
O A
O B
fox](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9f0815ea-ae36-403a-aa7b-ca3546051b89%2Fe03d755d-4119-466d-a780-d5d4ff308740%2Fikdto5i_processed.jpeg&w=3840&q=75)
Transcribed Image Text:13
Propionyl chloride is synthesized from "CO, in a 5-step synthesis. The intermediates are provided for each step. Identify the
missing reagents and identify the position of the labeled carbon atom in each intermediate. The C atom in carbon dioxide is
13
shown in a red color.
H2
reagent 1
CO2
H2
reagent 2
reagent 3
.C
A
H3C
MgBr
H3C
HO.
H;C
intermediate 3
intermediate 1
intermediate 2
reagent 4
H2
H2
.CI
reagent 5
K
H3C
H;C
C.
product: propionyl chloride
intermediate 4
Identify reagent(s) 1.
Which carbon is labeled 13C in intermediate 1?
O A
O B
fox
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