Consider an analyte solution of 50.0mL of 0.050M hydrochloric acid, HCl, titrated against 0.10 M sodium hydroxide, NaOH (the titration you will be performing in the lab!). (a)  What is the chemical equation representing the titration reaction? (b)  At the start of the titration, before any NaOH is added, what ions or molecules are present in the solution? You only need to list chemical species that are present in appreciable quantities - anything that is considered a small enough concentration to where you’d make a small-change approximation on an ICE table doesn’t need to be included. (c)  Which of species you identified in part (b) will determine the pH of the solution?

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter15: Additional Aqueous Equilibria
Section: Chapter Questions
Problem 123QRT: You are given four different aqueous solutions and told that they each contain NaOH, Na2CO3, NaHCO3,...
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Consider an analyte solution of 50.0mL of 0.050M hydrochloric acid, HCl, titrated against

0.10 M sodium hydroxide, NaOH (the titration you will be performing in the lab!).

  1. (a)  What is the chemical equation representing the titration reaction?

  2. (b)  At the start of the titration, before any NaOH is added, what ions or molecules are present in the solution? You only need to list chemical species that are present in appreciable quantities - anything that is considered a small enough concentration to where you’d make a small-change approximation on an ICE table doesn’t need to be included.

  3. (c)  Which of species you identified in part (b) will determine the pH of the solution?

  4. (d)  After adding 12.50mL of the NaOH, halfway to the equivalence point, what ions or molecules are present in the solution?

  5. (e)  At the equivalence point, after adding 25.00mL of NaOH, what ions or molecules are present in the solution?

  6. (f)  Which of the species you identified in part (e) will determine the pH of the solution?

  7. (g)  After adding 37.50mL of the NaOH, 50% past the equivalence point, what ions or molecules are present in the solution?

  8. (h)  Which of the species you identified in part (g) will determine the pH of the solution?

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