(e) Chemists often use thioacetals, in which the oxygen atoms of acetals are replaced by sulfur atoms, as protecting groups. As sulfur is directly beneath oxygen in the periodic table, you should be able to show the hydrolysis of a thioacetal such as the one below. S H₂O (large excess) HOTS
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- Curved arrows are used to illustrate the flow of electrons. In this reaction, a pi bond acts as a Bronsted base. Using the provided starting structures, draw the curved electron-pushing arrows for the acid-base reaction. Be sure to account for all bond-breaking and bond-making steps. Then draw the organic product of the reaction. Include all lone pairs in the structures. Ignore inorganic byproducts and counterions. H. | H H :CIⒸ Select to Add Arrows7) You want to synthesize 3-methyl-2-pentene from 2-chloro-3-methylpentane. Which reagent would you use? a. HCI, heat b. NH:(aq), 25°C c. CH:CO2NA, CH:CO2H, heat d. CH3CH2ONA, CH3CH2OH, heat e. CН:CH2ОН, heatAnswer all three parts plz. You are starting with three aryl bromides. They undergo a typical grignard reaction with magnesium metal and anhydrous ether (diethyl ether). Dry ice is then added to it and it is then cooled. Draw and label the names of the aryl carboxylic acids that will form for each. Part a) 4-bromonitrobenzene Part b) 4-bromotoluene Part c) 2-bromotoluene
- A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis gave CH3(CH2), CO₂H and HO₂CCH2CH2CH2CH2CO₂H as the only products. Draw a reasonable structure for this hydrocarbon. Click and drag to start drawing a structure. D:app.101edu.co Draw the product of the reaction shown below. Ignore inorganic byproducts. H2, Ni heat, pressure Drawing Q Benz CBn Draw the structure of the major organic product formed from the reaction below. Bn H ད ་ + HỌỌC. NH2 N DCC .... NH H Bn
- This question has multiple parts. Work all the parts to get the most points. meta-Chloroperoxybenzoic acid (m-CPBA) is not the only peroxy acid capable of reacting with alkenes to form epoxides. For the reaction below: H3C H3C CH₂ + CF3CO3H a Draw the structure of the major organic product derived from the alkene. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Use wedge and hash bonds ONLY when needed to show reaction stereochemistry. . If the reaction produces a racemic mixture, just draw one stereoisomer. 3*2 c C -> O 000 - IF1. Write the structure of the major organic product for reactions a, b and e? H₂C b. H₂c- CH, CH₂ Cold KMnO, OH A KMnO, H c. CH3CH₂-CH=CH-CH₂CH3 + H₂SO4 →A Moving to another question will save this response. Question 3 Which of the following statements about ethanethiol (CH3CH2SH) is(are) correct? O Ethanethiol will be effectively converted into its conjugate base through a reaction with sodium hydroxide (NAOH) O Ethanethiol is a good nucleophile which could react with a 1° alkyl halide in an SN2 reaction to produce a sulfide (thioether) O Ethanethiol can undergo oxidation by reaction with KMNO4 to produce a sulfonic acid O Statements 1 and 2 are correct O All of the statements are correct A Moving to another question will save this response. 080 acer FS F6
- Give the major product(s) of the following reaction. HO, heat CH;0" CH;OH O., HO. There is no reaction under these conditions or the correct product is not listed here.4. A CHEM 245 student wants to synthesize some ethylene glycol to use as antifreeze in his radiator this winter. He proposes the following reaction to his instructor, who quickly explains that this reaction won't work as proposed due to the student's choice of reagent. 1) NaH 2) H20 OH Но a) Why can't sodium hydride (NaH) be used as the nucleophile in the reaction above? b) Propose an alternate reagent that COULD be used with the ethylene oxide to successfully give the desired ethylene glycol product.Give the structure(s) of the organic product(s) formed, if any, in each of the following reactions. If no reaction occurs, write NR or no reaction. Circle major products when there are multiple. NH2 h. CH CH, (ехсess) NH 1) KOH 2) NH 3)H,N-NH,
