The structures of four complex ions are given. Each has Co³+ as the central ion. The ligands are H₂O, NH3, and oxalate ion, C₂O42-. Determine which, if any, of these complex ions are isomers (geometric or optical); which, if any, are identical (that is, have identical structures); and which, if any, are distinctly different. он2 H₂N H₂N OH₂ Co3+ OH₂ (a) NH3 Co3+ ГОН, OH₂ (c) OH₂ H₂O H₂O Co3+ он2 (b) NH3 NH3 CO3+ NH3 (d) NH3

Chemistry: The Molecular Science
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Author:John W. Moore, Conrad L. Stanitski
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Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
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The structures of four complex ions are given. Each has Co³+ as the central ion.
The ligands are H₂O, NH3, and oxalate ion, C₂O42-. Determine which, if any, of
these complex ions are isomers (geometric or optical); which, if any, are identical
(that is, have identical structures); and which, if any, are distinctly different.
OH₂
OH₂
H₂N
Da d
Co3+
ox
Co3+
H₂N
NH3
OH₂
(a)
ہے
OX
NH3
Co3+
OH₂
(c)
он2
LOH,
H₂O
H₂O
OH₂
(b)
NH3
Co3+
NH3
(d)
NH3
Transcribed Image Text:The structures of four complex ions are given. Each has Co³+ as the central ion. The ligands are H₂O, NH3, and oxalate ion, C₂O42-. Determine which, if any, of these complex ions are isomers (geometric or optical); which, if any, are identical (that is, have identical structures); and which, if any, are distinctly different. OH₂ OH₂ H₂N Da d Co3+ ox Co3+ H₂N NH3 OH₂ (a) ہے OX NH3 Co3+ OH₂ (c) он2 LOH, H₂O H₂O OH₂ (b) NH3 Co3+ NH3 (d) NH3
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