Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 12, Problem 28P
Interpretation Introduction
Interpretation:
The reason should be explained why iodine does not react with ethane, even though it is more easily cleaved homolytically than other halogens.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical.
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1. For the reaction (CH3)2O + C₂H5F → [(CH3)2OC₂H5]+F¯
(a) draw the structure for the cation
b) i) Draw the different structural isomers of the 6-membered ring compound
[GAAIBNPAS]H6 in which there are alternating Group 13 and 15 elements.
ii) The isomers containing both B-N and AI-N bonding are the most stable.
Explain why this is the case.
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iv) While borazine exists as a planar ring compound, the [GAAIBNPAS]H6 ring
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Using Friedel Crafts alkylation of benzene, a group of scientists discovered
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compound B is reacted with nitric acid, compound C, C3H,B1NO3, is formed.
While Friedel Crafts alkylation of compound A produces compound D. This
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Compound F, C10H1002, was produced by Friedel Crafts acylation of
compound A. This compound F reacts positively with alkaline iodine and 2,4-
dinitrophenylhydrazine. However, it returns negative results for Tollens' and
Benedict's tests.
Identify the possible structural formulae compounds A to F and explain your
answers.
Chapter 12 Solutions
Organic Chemistry (8th Edition)
Ch. 12.2 - Prob. 1PCh. 12.2 - Write the steps for formation of...Ch. 12.3 - Prob. 3PCh. 12.4 - How many alkyl chlorides are obtained from...Ch. 12.4 - Prob. 6PCh. 12.5 - Prob. 8PCh. 12.5 - a. Would chlorination or bromination produce a...Ch. 12.5 - Show how the following compounds could be prepared...Ch. 12.6 - Prob. 12PCh. 12.7 - Prob. 13P
Ch. 12.7 - Prob. 14PCh. 12.8 - Prob. 15PCh. 12.8 - Draw the stereoisomers of the major...Ch. 12.9 - Prob. 18PCh. 12.9 - How many allylic substituted bromoalkenes are...Ch. 12.9 - a. How many stereoisomers are formed from the...Ch. 12.9 - Prob. 21PCh. 12.9 - Prob. 22PCh. 12.10 - Prob. 23PCh. 12.11 - How many atoms share the unpaired electrons in...Ch. 12.11 - Prob. 25PCh. 12 - Prob. 26PCh. 12 - Prob. 27PCh. 12 - Prob. 28PCh. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Prob. 33PCh. 12 - Prob. 34PCh. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - Prob. 37PCh. 12 - a. What five-carbon alkene forms the same product...Ch. 12 - Prob. 39PCh. 12 - Starting with cyclohexane, how could the following...Ch. 12 - a. Propose a mechanism for the following reaction:...Ch. 12 - What stereoisomers are obtained from the following...Ch. 12 - Prob. 43PCh. 12 - Prob. 44PCh. 12 - Prob. 45PCh. 12 - Draw the products of the following reactions,...Ch. 12 - Prob. 47PCh. 12 - Prob. 48PCh. 12 - Prob. 49PCh. 12 - Explain why the rate of bromination of methane...Ch. 12 - Prob. 51PCh. 12 - Prob. 1PCh. 12 - Prob. 2PCh. 12 - Prob. 3PCh. 12 - Prob. 4P
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