Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 19, Problem 19.35SP
In each pair of compounds, select the stronger base, and explain your choice.
- a. HOCH2CH2NH2 or CH3CH2NH2
- b. PhNH2 or PhCH2NH2
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Which is a stronger base?a. HS− or HO− c. CH3OH or CH3O−d. Cl− or Br− b. CH3O− or CH3NH
−
CH3COO− or CF3COO−CH3CHClCOO− or CH3CHBrCOO−
Which is the more stable base? a. Br− or I− b. CH3O− or CH3S− c. CH3CH2O− or CH3COO− d. H2C CH or HC C− e. FCH2CH2COO− or CH2CH2COO- f. CLCH2CH2O- or CL2CHCH2O-
4. Which of the following is the strongest base?
A. (CH3)3COH
B. CH3CH₂NH™
C. H₂O
D. CH3NH2
Chapter 19 Solutions
Organic Chemistry (9th Edition)
Ch. 19.2A - Prob. 19.1PCh. 19.2B - Prob. 19.2PCh. 19.2B - Give correct names for the following amines:Ch. 19.3 - Prob. 19.4PCh. 19.4 - Prob. 19.5PCh. 19.6 - Rank each set of compounds in order of increasing...Ch. 19.8A - Prob. 19.7PCh. 19.8C - Prob. 19.8PCh. 19.8C - Prob. 19.9PCh. 19.8D - a. Show how fragmentation occurs to give the base...
Ch. 19.10B - Propose a mechanism for nitration of pyridine at...Ch. 19.10B - Prob. 19.12PCh. 19.10C - Prob. 19.13PCh. 19.10C - Prob. 19.14PCh. 19.11 - Propose a mechanism to show the individual...Ch. 19.11 - Prob. 19.16PCh. 19.12 - Give the products expected from the following...Ch. 19.13 - Prob. 19.18PCh. 19.13 - Prob. 19.19PCh. 19.14 - Prob. 19.20PCh. 19.15 - Prob. 19.21PCh. 19.15 - Prob. 19.22PCh. 19.16 - Prob. 19.23PCh. 19.17 - Prob. 19.24PCh. 19.17 - Prob. 19.25PCh. 19.18 - Prob. 19.26PCh. 19.19 - Prob. 19.27PCh. 19.20A - Addition of one equivalent of ammonia to...Ch. 19.20A - Prob. 19.29PCh. 19.20B - Show how you would accomplish the following...Ch. 19.20C - Prob. 19.31PCh. 19 - For each compound, 1. classify the...Ch. 19 - Prob. 19.33SPCh. 19 - Within each structure, rank the indicated...Ch. 19 - In each pair of compounds, select the stronger...Ch. 19 - Which of the following compounds are capable of...Ch. 19 - Complete the following proposed acid-base...Ch. 19 - Predict the products of the following reactions:...Ch. 19 - Prob. 19.39SPCh. 19 - Show how m-toluidine can be converted to the...Ch. 19 - The mass spectrum of tert-butylamine follows shows...Ch. 19 - Prob. 19.42SPCh. 19 - The following drugs are synthesized using the...Ch. 19 - Prob. 19.44SPCh. 19 - Synthesize from benzene. (Hint: All of these...Ch. 19 - Propose mechanisms for the following reactions.Ch. 19 - Prob. 19.47SPCh. 19 - Prob. 19.48SPCh. 19 - Prob. 19.49SPCh. 19 - Show how you can synthesize the following...Ch. 19 - Prob. 19.51SPCh. 19 - The alkaloid coniine has been isolated from...Ch. 19 - A chemist is summoned to an abandoned...Ch. 19 - Pyrrole undergoes electrophilic aromatic...Ch. 19 - Prob. 19.55SPCh. 19 - Prob. 19.56SPCh. 19 - An unknown compound shows a weak molecular ion at...Ch. 19 - A compound of formula C11H16N2 gives the IR,...Ch. 19 - (A true story.) A drug user responded to an ad...Ch. 19 - Prob. 19.60SPCh. 19 - Prob. 19.61SPCh. 19 - Prob. 19.62SPCh. 19 - Prob. 19.63SPCh. 19 - Prob. 19.64SPCh. 19 - Prob. 19.65SP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Which is a stronger base? a. HS− or HO− b. CH3O− or CH3NH c. CH3OH or CH3O d. Cl− or Br− e. CH3COO− or CF3COO− f. CH3CHClCOO− or CH3CHBrCOO−arrow_forwardWhich member of each pair is the stronger base? a. ethylamine or aniline b. ethylamine or ethoxide ion c. phenolate ion or ethoxide ion d. phenolate ion or acetate ionarrow_forward2) Determine which molecule is the stronger base. a. b. NH2 Vs Vs NH NH CIarrow_forward
- Determine which has stronger base between given compounds: 1. A. HOCH2CH2NH2 or B. CH3CH2NH2 2. please refer to imagearrow_forwardWhich is a stronger acid? a. HCl or HBr b. CH3CH2CH2NH3 or CH3CH2CH2OH2 c. CH3CH2CH2OH or CH3CH2CH2SHarrow_forwardQuestion 5 5. Rank each of the five compounds by relative basicity. Use a "1" for the strongest base, a "2" for the 2nd strongest, all the way to a "5" for the weakest base. NH2 ZHN NH2 Meo NH2 NH2 O2Narrow_forward
- 1. Circle the strongest base. -NH₂ -NH₂ farrow_forward1. Consider the following unequal equilibrium. Which two species in this equilibrium represent the weaker acid and the weaker base? CH3CH3 + CH3NH 1 2 O 1 and 4 2 and 3 1 and 2 3 and 4 ? → CH3CH₂ 3 CH3NH₂ 4arrow_forwardWhich of the following indicated a-hydrogens is most acidic? ဝ CH3CH₂CH CH3CH₂CCH₂CH₂CH3 CH3CH₂CCH₂COCH₂CH3 ပင်,H CCH₂ COCHICH A. CH3CH₂COCH₂CH3 D. B. C. ₂CCH₂C CH3CH₂CCH₂CH3 E.arrow_forward
- 5. Rank each of the five compounds by relative basicity. Use a "1" for the strongest base, a "2" for the 2nd strongest, all the way to a "5" for the weakest base. NH2 NH2 NH2 MeO NH2 NH2 O2Narrow_forwardWhich C-H bonds in the following molecules are acidic because the resulting conjugate base is resonance stabilized? а. b. CH3CH2CH2-CN c. d. CH CH,CH,CHs CH,CH,CH OCH,CH3 CH3arrow_forwardDraw the structure of a constitutional isomer of compound B that fits each description. a. an isomer that is at least 105 times more acidic than B b. an isomer that is at least 10 times less acidic than B c. an isomer that is comparable in acidity to B HO. Barrow_forward
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General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY