Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 23, Problem 37DSP
Interpretation Introduction
Interpretation:
The major product of the given reaction isto be determined.
Concept Introduction:
Substitutents attached to an
Lithiation usually occurs at the carbon atom ortho to the substituent.
These ortho-lithiated derivatives undergo the normal reactions similar to organolithium reagents.
Organolithium reagents react with dimethyl formamide to form a tetrahedral intermediate which upon hydrolysis results in formylation.
Amides undergo hydrolysis in acidic medium to form
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
The two reactions that follow involve nucleophilic substitution at an acyl carbon.
For each reaction, show the electrophile and the nucleophile in the key bond-
forming step, the corresponding tetrahedral addition intermediate, and the leaving
group in the bond-breaking step. Write a general mechanistic scheme (use curved
arrows to show bond-making and bond-breaking processes) for these reactions,
keeping in mind that acid- and base-catalyzed processes will differ in their timing
of proton transfers.
00
|| ||
PhCOCPh+ C₂H5OH
00
||||
PhCOCPh+ 2 CH3NH
H₂SO4 cat.
O
PhCOC₂H5+ PhCO₂H
PhCNCHg + CH3NH PhCO
I need a detailed diagram or table of every reaction
in organic of: alcohol, aldehyde, ketone, epoxide,
ester, ether, amide, anhydride, carboxylic acid, and
functional derivatives of carboxylic acid. How to go
from one to another, and the elaborated cycle of the
reactions
Give the major organic product generated by the following reaction
Chapter 23 Solutions
Organic Chemistry - Standalone book
Ch. 23.1 - Prob. 1PCh. 23.3 - Problem 23.2 One of the hydroxybenzoic acids is...Ch. 23.4 - Prob. 3PCh. 23.5 - Prob. 4PCh. 23.6 - Problem 23.5 The compound shown was required for...Ch. 23.8 - Prob. 6PCh. 23.8 - Prob. 7PCh. 23.9 - Prob. 8PCh. 23.9 - Prob. 9PCh. 23.10 - Prob. 10P
Ch. 23.12 - Prob. 11PCh. 23 - The IUPAC rules permit the use of common names for...Ch. 23 - Prob. 13PCh. 23 - Prob. 14PCh. 23 - Prob. 15PCh. 23 - Prob. 16PCh. 23 - Prob. 17PCh. 23 - Prob. 18PCh. 23 - Prob. 19PCh. 23 - Prob. 20PCh. 23 - Prob. 21PCh. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Choose the reaction in each of the following pairs...Ch. 23 - Pentafluorophenol is readily prepared by heating...Ch. 23 - Prob. 29PCh. 23 - Treatment of p-hydroxybenzoic acid with aqueous...Ch. 23 - Prob. 31PCh. 23 - Prob. 32PCh. 23 - Treatment of 2,4,6-tri-tert-butylphenol with...Ch. 23 - Prob. 34PCh. 23 - Prob. 35PCh. 23 - Prob. 36DSPCh. 23 - Prob. 37DSPCh. 23 - Prob. 38DSPCh. 23 - Prob. 39DSP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Enamines normally react with methyl iodide to give two products: one arising from alkylation at nitrogen and the second arising from alkylation at carbon. For example, Heating the mixture of C-alkylation and N-alkylation products gives only the product from C-alkylation. Propose a mechanism for this isomerization.arrow_forwardSuppose you have a mixture of these three compounds. Devise a chemical procedure based on their relative acidity or basicity to separate and isolate each in pure form.arrow_forwardGive the major organic product of the following reactions.arrow_forward
- Give the clear handwritten answer and complete the reactionarrow_forwardIn electrophilic aromatic substitution reaction by drawing the structures of the compounds given below Explain which products will be formed as a result of its reaction with the nitronium ion.methoxybenzene, benzoic acidarrow_forwardDescribe a sequence of reactions for the following reactionarrow_forward
- Suggest reagents and reaction conditions for each of the following reactionsarrow_forwardGive the reagents necessary for the synthesis above and please show the detailed step-by-step mechanism.arrow_forwardOrganoboranes, such as 1 or 2, are Lewis acids and are observed to be electrophilic in their reactions with other compounds, esp. alkenes. Using your knowledge of molecular structure, explain this observation. That is, what makes organoboranes such good Lewis acids?arrow_forward
- Enamines can serve as enolate surrogates in reactions at the a-carbon. In the reaction sequence, the structures of the enamine addition product – the initial iminium and its neutral tautomer – are shown. Draw the structures of the enamine and alkyl bromide reactants that would combine to form these intermediates, and draw the structure of the final product, obtained via hydrolysis of the neutral intermediate. iminium intermediate neutral intermediate tautomerization N. Reactants H20 hydrolysis product Draw the enamine and alkyl bromide reactants. Draw the hydrolysis product. ZIarrow_forwardGive the reaction mechanism for ETHYNE and bromine solution. Draw and explain the steps of the reaction mechanism.arrow_forwardSubstitutions on aromatic rings are generally carried out by electrophilic substitution, but for the synthesis of phenolic compounds and alkoxy benzene it is carried out by nucleophilic substitution, explain why this is so .arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning
Characteristic Reactions of Benzene and Phenols; Author: Linda Hanson;https://www.youtube.com/watch?v=tjEqEjDd87E;License: Standard YouTube License, CC-BY
An Overview of Aldehydes and Ketones: Crash Course Organic Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=-fBPX-4kFlw;License: Standard Youtube License