Inorganic Chemistry
5th Edition
ISBN: 9780321811059
Author: Gary L. Miessler, Paul J. Fischer, Donald A. Tarr
Publisher: Prentice Hall
expand_more
expand_more
format_list_bulleted
Question
Chapter 3, Problem 3.27P
Interpretation Introduction
Interpretation: The structures of
Concept introduction: A molecule may have multiple possible structures. But the structure taken into consideration is the most stable structure. For maximum stability, the repulsions must be minimum. The electron pairs must be aligned at proper angles so that the repulsions are to the least extent.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
W
Which of the following is most likely to be a solid at room temperature?
3
HF
H₂O
Na₂S
N₂
NH3
E
R
T
Y
7
&=
U
00
the answer is NOT
CN–, OAc–, F–, ClO4–
i got it wrong when I chose this one
S8+o2= so3
Chapter 3 Solutions
Inorganic Chemistry
Ch. 3.1 - Use electron-dot diagrams and formal charges to...Ch. 3.2 - Predict the structures of the following ions....Ch. 3.2 - Prob. 3.3ECh. 3.2 - Which molecule has the smallest bond angle in each...Ch. 3.2 - Briefly account for the following observations: a....Ch. 3.2 - Does this approach work for different steric...Ch. 3 - The dimethyldithiocarbamate ion, [S2CN( CH 3 )2]-...Ch. 3 - Several resonance structures are possible for each...Ch. 3 - Draw the resonance structures for the...Ch. 3 - Three isomers having the formula N2CO are known:...
Ch. 3 - Show the possible resonance structures for nitrous...Ch. 3 - Nitric acid, which exists as HNO3 molecules in the...Ch. 3 - L. C. Allen has suggested that a more meaningful...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Give Lewis dot structures and sketch the shapes of...Ch. 3 - Explain the trends in bond angles and bond lengths...Ch. 3 - Select from each set the molecule or ¡on having...Ch. 3 - a. Compare the structures of the azide ion, N3 ,...Ch. 3 - Consider the series OCl2,O( CH3)2 , and O( SiH3)2...Ch. 3 - Two ions isoelectronic with carbon suboxide, C3O2...Ch. 3 - Explain the following: a. Ethylene, C2H4 , is a...Ch. 3 - Explain the following: a. PCI5 is a stable...Ch. 3 - X-ray crystal structures of ClOF3 and BrOF3 have...Ch. 3 - Make the following comparisons about the molecules...Ch. 3 - Prob. 3.20PCh. 3 - A solution containing the lO2F2 ion reacts slowly...Ch. 3 - The XeOF3 anion has been reported recently (D. S....Ch. 3 - Predict the structure of l(CF3)Cl2 . Do you expect...Ch. 3 - a. Which has the longer axial PF distance, PF2(...Ch. 3 - Prob. 3.25PCh. 3 - SeCl62,TeCl62 , and CIF6 are all octahedral, but...Ch. 3 - Prob. 3.27PCh. 3 - The thiazyldichloride ion, NSCl2- , is...Ch. 3 - Sketch the most likely structure of PCl3Br2 and...Ch. 3 - a. Are the CF3 groups in PCl3( CF3)2 more likely...Ch. 3 - Of the molecules C1SO2CH3,C1SO2CF3 , and ClSO2CCl3...Ch. 3 - Prob. 3.32PCh. 3 - Prob. 3.33PCh. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Although the CF distances and the FCF bond angles...Ch. 3 - The Cl...Cl distance in CCl4 is 289 pm, and the...Ch. 3 - The FCF angle in F2CO , shown here, is 109.5°; the...Ch. 3 - Compounds in which hydrogen is the outer atom can...Ch. 3 - For each of the following bonds, indicate which...Ch. 3 - Give Lewis dot structures and shapes for the...Ch. 3 - Give Lewis dot structures and sketch the shapes...Ch. 3 - Which of the molecules in Problem 3.41 are polar?Ch. 3 - Which of the molecules in Problem 3.42 are polar?Ch. 3 - Prob. 3.45PCh. 3 - Prob. 3.46P
Knowledge Booster
Similar questions
- < S TA C9 D B 20 O +:arrow_forwardSome of the physical properties of H2O and D2O are as follows: Property H2O D2O Density at 20C (g/ml) 0.997 1.108 Boiling point (C) 100.00 101.41 Melting point (C) 0.00 3.79 Hvap(kJ/mol) 40.7 41.61 Hfus (kJ/mol) 6.02 6.3 Account for the differences. (Note: D is a symbol often used for 2H, the deuterium isotope of hydrogen.)arrow_forwardConsider the possible structures N₂O4 shown below. 0 N-O=N-O: 0 0 N=O-N=O 4 * N-0-N=0: Structure 5 Structure 1 10: 0 " N=O=N-O: Z N-O=N=O N-O-N-O 05 10: 1 N-O-N-O: "1 :0: :0: 11 N-O=N-O: 1 :0: N-O-N=O :0 Based on formal charges, how would you describe the bonding arrangement shown in the following structures. (compared to the other structures shown), 10: N-O-N=O १ Would structure #7 be more likely or less likely than structure #6? How many of the resonance structures would you describe as "Very Likely"? Based on the relative likelihood of these possibilities, determine the average bond order for the internal N-O bond in the molecule (indicated by the arrow in the picture below. If your answer is a fraction, enter that fraction as the decimal equivalent (i.e. 11/3 = 1.333, etc.) Average Bond Order =arrow_forward
- Use the following set of assumptions to estimate the CN bond length in fulminic acid: 1) only the two best structures contribute to the true structure 2) the best structure contributes 75%, 3) the CN single bond is 1.47 pm, the double is 1.32 pm and the triple is L.16 pm. Enter your answer with 2 significant figures as a number with no units. Structure I Structure II Structure III H-C=N=0 H-C=N-0 ŌI H-C-N=01 VFullsc 10:41 PMarrow_forwardMilk of magnesia with [H3O+] = 2.0 X 10-9Marrow_forwardN= conc. HNO3, (CF₂ Co₂0 Na₂ S₂05 -NO₂ CNarrow_forward
- an unknown has the formula C₆H₁₂O. The IR spectrum of this substance has a strong vibration near 1700 cm⁻¹ . Which structure below is consistent with these data?arrow_forwardGiven the following data: 2 H₂(g) + O₂(g) → 2 H₂O(g) C₂H4(g) + 3 O₂(g) → 2 CO₂(g) + 2 H₂O(g) 2 CzHo(g) +7 Oz(9) → 4 CO,(g) + 6 H20(g) calculate AH for the reaction C₂H₂(g) + H₂(g) → C₂H₂(g). kJ ΔΗ = −484 kJ AH-1323 kJ ΔΗ = -2857 kJarrow_forwardDraw the skeletal (line-bond) structure of isopropyl butanoate. I I 1 I U J S I 1 1 1 1 I 1 A S 1 1 1 1 I I Drawing U I I I I I Iarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning