Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Question
Chapter 9, Problem 25QAP
Interpretation Introduction
Interpretation:
The given molecules are to be arranged in order of decreasing boiling point.
Concept introduction:
The temperature at which the vapor pressure of a liquid equals the external pressure surrounding the liquid is known as the boiling point.
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(a)
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Which of the following boils at the highest temperature?
(a) CH4
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(c) C4H10
(d) C5H12
Which substance has the higher boiling point? Explain.(a) CH₃CH₂OH or CH₃CH₂CH₃(b) NO or N₂(c) H₂S or H₂Te
Chapter 9 Solutions
Chemistry: Principles and Reactions
Ch. 9 - Prob. 1QAPCh. 9 - Prob. 2QAPCh. 9 - The vapor pressure of I2(s) at 30C is 0.466 mm Hg....Ch. 9 - Prob. 4QAPCh. 9 - Trichloroethane, C2H3Cl3 is used as a degreaser...Ch. 9 - p-Dichlorobenzene, C6H4Cl2, can be one of the...Ch. 9 - Prob. 7QAPCh. 9 - Dichloromethane, CH2Cl2,is widely used as a...Ch. 9 - Prob. 9QAPCh. 9 - Prob. 10QAP
Ch. 9 - At a resort in Sante Fe, New Mexico, the...Ch. 9 - Prob. 12QAPCh. 9 - Prob. 13QAPCh. 9 - Consider the following data for the vapor pressure...Ch. 9 - Referring to Figure 9.7, state what phase(s)...Ch. 9 - Referring to Figure 9.7, state what phase(s) is...Ch. 9 - Prob. 17QAPCh. 9 - Consider the phase diagram of the compound in...Ch. 9 - Prob. 19QAPCh. 9 - Prob. 20QAPCh. 9 - Given the following data about xenon,...Ch. 9 - Given the following data about CO2: • triple...Ch. 9 - A pure substance X has the following properties:...Ch. 9 - Prob. 24QAPCh. 9 - Prob. 25QAPCh. 9 - Arrange the following compounds in order of...Ch. 9 - Which of the following would you expect to show...Ch. 9 - Which of the following compounds would you expect...Ch. 9 - Prob. 29QAPCh. 9 - Prob. 30QAPCh. 9 - Explain in terms of forces between structural...Ch. 9 - Prob. 32QAPCh. 9 - Prob. 33QAPCh. 9 - In which of the following processes is it...Ch. 9 - For each of the following pairs, choose the member...Ch. 9 - Follow the directions for Question 35 for the...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - What are the strongest attractive forces that must...Ch. 9 - Prob. 39QAPCh. 9 - Prob. 40QAPCh. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Of the four general types of solids, which one(s)...Ch. 9 - Prob. 43QAPCh. 9 - Prob. 44QAPCh. 9 - Give the formula of a solid containing Si that is...Ch. 9 - Prob. 46QAPCh. 9 - Prob. 47QAPCh. 9 - Describe the structural units in (a) C (graphite)...Ch. 9 - Molybdenum has an atomic radius of 0.145 nm. The...Ch. 9 - Nickel has an atomic radius of 0.162 nm. The edge...Ch. 9 - Lead (atomicradius=0.181nm) crystallizes with a...Ch. 9 - Iridium crystallizes in a face-centered unit cell....Ch. 9 - In the LiCl structure shown in Figure 9.21, the...Ch. 9 - Potassium iodide has a unit cell similar to that...Ch. 9 - Prob. 55QAPCh. 9 - Consider the CsCl cell (Figure 9.21). The ionic...Ch. 9 - Consider the sodium chloride unit cell shown in...Ch. 9 - Consider the CsCl unit shown in Figure 9.21. How...Ch. 9 - A 1.25-L clean and dry flask is sealed. The air in...Ch. 9 - Aluminum metal crystallizes with a face-centered...Ch. 9 - Consider a sealed flask with a movable piston that...Ch. 9 - Prob. 62QAPCh. 9 - Prob. 63QAPCh. 9 - Prob. 64QAPCh. 9 - Chloroform, CHCl3, has a normal boiling point of...Ch. 9 - Prob. 66QAPCh. 9 - Prob. 67QAPCh. 9 - In the blanks provided, answer the questions...Ch. 9 - Answer the questions below, by filling in the...Ch. 9 - Prob. 70QAPCh. 9 - Prob. 71QAPCh. 9 - What is the difference between (a) a covalent bond...Ch. 9 - Four shiny solids are labeled A, B, C, and D....Ch. 9 - Prob. 74QAPCh. 9 - The following data are given for CC14:...Ch. 9 - Iron crystallizes in a body-centered unit cell....Ch. 9 - Prob. 77QAPCh. 9 - Trichloroethane, C2H3Cl3, is the active ingredient...Ch. 9 - Prob. 79QAPCh. 9 - Prob. 80QAPCh. 9 - Prob. 81QAP
Knowledge Booster
Similar questions
- (a) Place the following substances in order of increasingvolatility: CH4, CBr4, CH2Cl2, CH3Cl, CHBr3, and CH2Br2.(b) How do the boiling points vary through this series?(c) Explain your answer to part (b) in terms of intermolecularforces.arrow_forward6. Ethanoic acid (CH3COOH) has a much lower vapor pressure than ethanol (CH3CH2OH). What is the most reasonable explanation? (A) The polarizability of two oxygen atoms increases the London forces of attraction in ethanoic acid compared with ethanol. (B) Hydrogen bonding in ethanoic acid is the strongest attractive force and is mainly responsible for the observed data. (C) Both ethanol and ethanoic acid have an – OH, so the difference is the dipole of the second oxygen that increases the attractive forces. (D) Ethanol has an - OH group and can hydrogen bond; therefore, the London forces must cause the effect.arrow_forwardRank the following in order of decreasing(a) Boiling point: O₂, Br₂, As(s)(b) ΔH(vap): Cl₂, Ar, I₂arrow_forward
- 2. Circle all the compounds in the following list which would be expected to form intermolecular hydrogen bonds in the liquid state: (a) CH3OCH3 (dimethyl ether) (f) CH3OH (methanol) (b) CН4 (c) HF (d) CH3CO2H (acetic acid) (e) Br2arrow_forward5. Arrange the following compounds in the order of decreasing strength of London dispersion forces. (a) CCI4, CF4, CBr4 (b) CH4, CH3CH3, CH3CH2CH3 (c) Ar, He, Nearrow_forwardWhich of the following gases is expected to be most soluble in water? Explain your reasoning.(a) CH4(b) CCl4(c) CHCl3arrow_forward
- Which compound is expected to exhibit the highest vapor pressure at 25°C. (A) C,H5CH3 (B) C6H5CI (C) C,H5NH2 (D) C6H5OHarrow_forwardDoes SF₆(boiling point 16C at 1 atm) behave more ide-ally at 150C or at 20C? Explain.arrow_forwardWhich would you expect to have the higher boiling point, the hydrocarbon fuel butane, C4H10, or the organic solvent acetone. (CH3)2CO?arrow_forward
- Which member in each pair of liquids has the higher vapor pressure at a given temperature? Explain.(a) C2H6 or C4H10 (b) CH3CH2OH or CH3CH2F(c) NH3 or PH3arrow_forward17. Which one of the following substances can be melted without breaking chemical bonds? (a) sodium sulfate (b) zinc chloride (c) sulfur dioxide (d) silicon dioxide (e) diamondarrow_forwardAt the normal boiling point of benzene,arrow_forward
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