Explain the differences between the following calibration methods and why they are needed. a) External standard; b) Standard addition; c) Internal standard
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Explain the differences between the following calibration methods and why they are needed. a) External standard; b) Standard addition; c) Internal standard
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- You are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.Analytical chemistry is a particular field within the broader spectrum of the chemical sciences, in which many times the focus of analytical experiments is to develop new methods to analyze compounds, either structurally or by determining concentrations of compounds. One of the processes analytical chemists use to determine the exact concentration of a working solution is called standardization. In your own words, describe the differences between a primary, secondary, and tertiary standard, and describe the underlying concept behind the standardization process. Why is it done?There are numerous considerations when choosing an internal standard. give three reasons why 1,4-dioxane will serve as an effective internal standard.
- Classify the statements based on whether they describe the method of standard addition, the method of external calibration, or both.What are the differences between systematic and random errors and how do they effect accuracy and precision? In what circumstances would you use standard addition (versus a normal calibration curve) to determine the amount of an analyte in a sample? A urine sample, containing analyte Z is analysed by the standard addition method where 5 mL of the original sample was mixed with increasing amounts of a Z standard and each solution diluted to a volume of 50 mL prior to analysis. A plot of the final concentration of the standard in each of the 50 mL samples (x axis) versus The measured signal from the analysis of each 50 mL sample (on y axis) produced a straight line with the general equation: y = 44.72x + 4.06 what was the final concentration of Z in the 50 mL standard addition sample? what was the initial concentration of Z in the original urine sample?(a) For use in an iodine titration, you prepare a solution from 0.222 2 (+0.000 2) g of KIO3 [FM 214.001 0 (+0.000 9)] in 50.00 (+0.05) mL. Find the molarity and its uncertainty with an appropriate number of significant figures. (b) Would your answer be affected significantly if the reagent were only 99.9% pure?
- What is the purpose of a calibration curve in analytical chemistry?Titration purity NxVx mEq weight weight of sample (g) x 100 Volume (Weight of sample (g) Nx mEw Weight V = 100 Normality Weight of sample (g) Vx mEw Weight N = 100 mEq Weight mEq Weight % x Weight of sample (g) V xN /100 Weight of sample Nx Vx mEq weight (9)= x 100 %3D % Purity Volume 2 Normality 1 Normality 2 Volume 1For the following reaction, calculate the value of Q. 3A - 4B + 2C 1 [A] 0.42 [B] = 0.82 [C] = 0.90 To avoid possible rounding errors report your answer to three significant figures. On your scrap paper you should report the proper number of significant figures if correct answer has more or less than three.
- 1a. List THREE (3) advantages of internal standardization method than normal calibration.professor Scimemi has accepted you as a Master’s student and you are involved in a project that studies the cellular basis of neuropsychiatric diseases. For your electrophysiology recordings you have to make a recording solution containing (in mM): 119 NaCl, 2.5 KCl, 2.5 CaCl2, 1 MgCl2, 26.2 NaHCO3, 1 NaH2PO4, 22 glucose. You need 800 ml of it. How much KCl do you need to weigh out? Hint: we only care about KCl here. (MW KCl is 74.55 g/molThe method of standard additions was used to determine nitrite in a soil sample. A 1.00-mL portions of the soil extract sample was transferred to four 25-mL volumetric flasks. To each flask, increment volumes of a 1.00 x10-3M nitrite was added according to the table below. A colorimetric reagent was added to each flask to convert the nitrite into a colored product, and finally diluted to volume. What is the concentration of the nitrite in the soil extract based on the absorbance data below (with blank correction included)? Vol. of standard nitrite added, ml Absorbance 5.00 0.079 10.00 0.161 15.00 0.236 20.00 0.318 25.00 0.403