(a)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl
The examples of the organometallic compound are ethyl magnesium bromide and
Ether is used as a solvent for the Grignard reactions.
(b)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl halides, alkyl halides and aryl halides gives organometallic compound as a product.
The examples of the organometallic compound are ethyl magnesium bromide and
Organometallic compounds are used in organic synthesis, industries, as a catalyst and have many other uses.
Ether is used as a solvent for the Grignard reactions.
(c)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl halides, alkyl halides and aryl halides gives organometallic compound as a product.
The examples of the organometallic compound are ethyl magnesium bromide and
Organometallic compounds are used in organic synthesis, industries, as a catalyst and have many other uses.
Ether is used as a solvent for the Grignard reactions.
(d)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl halides, alkyl halides and aryl halides gives organometallic compound as a product.
The examples of the organometallic compound are ethyl magnesium bromide and
Organometallic compounds are used in organic synthesis, industries, as a catalyst and have many other uses.
Ether is used as a solvent for the Grignard reactions.
(e)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl halides, alkyl halides and aryl halides gives organometallic compound as a product.
The examples of the organometallic compound are ethyl magnesium bromide and
Organometallic compounds are used in organic synthesis, industries, as a catalyst and have many other uses.
Ether is used as a solvent for the Grignard reactions.
(f)
To determine: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents.
Interpretation: The synthesis of the given compound starting from bromobenzene and any other solvents and reagents is to be shown.
Concept introduction: The reaction of metals like lithium and magnesium with vinyl halides, alkyl halides and aryl halides gives organometallic compound as a product.
The examples of the organometallic compound are ethyl magnesium bromide and
Organometallic compounds are used in organic synthesis, industries, as a catalyst and have many other uses.
Ether is used as a solvent for the Grignard reactions.
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Chapter 10 Solutions
Organic Chemistry (9th Edition)
- Reagents a. C6H5CHO b. NaOH, ethanol h. BrCH2CH=CH2 i. Na* OEt, ethanol j. Br2, H* k. K* t-BuO c. Pyrrolidine, cat. H* d. H2C=CHCN e. H3O* f. I. CH2(CO2ET)2 -CH2CH2CN LDA m. heat g. ELOC(=0)CO2ET Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).arrow_forwardCyclopentanone is treated with chlorine (Cl2) in the presence of acid (H*). What product is formed? A. Chlorocyclopentane B. 1-chloro-1-hydroxycyclopentane C. 2-chlorocyclopentanone D. 3-chlorocyclopentanonearrow_forwardShow how to convert cyclohexanol to these compounds. a. Cyclohexene b. Cyclohexane c. Cyclohexanone d. Bromocyclohexanearrow_forward
- CH2 H3C H3C COOH Reagents e. PB13 f. NaCN then H3O* g. NBS, CCI4 h. CrO3, H2SO4 а. HBr b. Mg, ether c. CO2, ether then H3O* d. BH3, THF then H2O2, OH"arrow_forward2-Methyl-2-butene reacts with HBr in the presence of peroxide to give a. a secondary alkyl bromide. b. a primary alkyl bromide. c. a tertiary alkyl bromide. d. a vicinal dibromide.arrow_forwardAlkyl halide can be prepared from the addition of H-X to alkenes. Identify the product in the reaction. H-Br Select one: a. 1,2-dibromo-2-methylpropane b. 1-bromo-2-methylpropane c. t-butyl bromide (or 2-bromo-2-methylpropane) d. 2-methylpropanearrow_forward
- Reagents available f. PBr3 g. Mg, ether a. CH3CH,COCH b. C6H5 COCI c. AlCl3 d. NaBH₁, ethanol e. H₂SO4, dil am h. H₂SO4, conc i. SOCI₂ j. C6H5 CNarrow_forwardGive the products formed when benzaldehyde and benzoic acid are treated with the given reagents. a. Tollen’s reagentb. phenylhydrazine, H+c. HCNd. NH2OHe. 1 mole H2, Nif. 1 mole CH3OH, H+g. LiAlH4 then H2O, H+h. 2 moles CH3OH, H+i. CH3MgCl, then H2O, H+j. H2Oarrow_forwardcompound a HC=CH a. b. compound f Reagents HCI HBr H₂O, H₂SO4 C. d. Br₂ e. Cl₂ r compound d compound j compound i n compound h compound c compound b n HC=CH m. n. O. compound g compound e HC=CH 2 equivalents of NaNH₂ H₂, Lindlar's catalyst Na/NH3 p. H₂SO4, HgSO4 q. (sia)₂BH then H₂O₂, NaOH Prarrow_forward
- Consider the reaction of 2-bromo-2-methylpropane with water, shown below, to answer the following question(s). CH3 CH3 H₂C-C-Br H₂C-C-OH I CH3 CH3 Diagram 1: The first step of this reaction is shown below. CH3 CH3 H₂C-C Br I CH3 H₂C- a. b. CH3 B Diagram 2: The second and third steps of the reaction are shown below. CH₂ CH₂ CH₂ C. CH₂ d. 10 a carbene a carbanion H₂O a carbocation a radical 2) Refer to Diagram 1 and 2. Species B is: H H₂C- H + HC-C- H H + HBr Br 1 ÖH₂2 H₂C- H + H₂O*arrow_forwardThe reaction will produce which of the following results? A. Decolorization of a brown solution B. Production of a brown precipitate C. Acidification of a solution D. Production of fumes What property is expected in the organic product in the reaction? A.Solubility in alcohol is increased B.Polarity of the compound is decreased C.A cis-configuration is expected. D. The electrophile becomes a nucleophile. Which among the reactants is a reducing agent? A.Alkene B.MnO4, anion C.Water D. All of the Abovearrow_forwardSelect the product of the reaction below. A. B. O A O Br Br HBr C. Question 50 D. ? Brarrow_forward
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