Concept explainers
(a)
Interpretation: The bond angles about each highlighted atom needs to be predicted using the VSEPR model.
Concept Introduction: According to VSEPR model, geometry and bond angles of an atom can be determined from its hybridization which can be determined from the number of bond pairs and lone pair of electrons associated with it.
The Lewis structure of compound plays an important role here as it involves the arrangement of valence electrons which tells about the actual number of bond pair and lone pair present in an atom.
(b)
Interpretation: The bond angles about each highlighted atom needs to be predicted using the VSEPR model.
Concept Introduction: According to VSEPR model, geometry and bond angles of an atom can be determined from its hybridization which can be determined from the number of bond pairs and lone pair of electrons associated with it.
The Lewis structure of compound plays an important role here as it involves the arrangement of valence electrons which tells about the actual number of bond pair and lone pair present in an atom.
(c)
Interpretation: The bond angles about each highlighted atom needs to be predicted using the VSEPR model.
Concept Introduction: According to VSEPR model, geometry and bond angles of an atom can be determined from its hybridization which can be determined from the number of bond pairs and lone pair of electrons associated with it.
The Lewis structure of compound plays an important role here as it involves the arrangement of valence electrons which tells about the actual number of bond pair and lone pair present in an atom.
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
Introduction To General, Organic, And Biochemistry
- Indicate which of the following molecules are polar. Draw the molecular structure of each polar molecule, including the arrows that indicate the bond dipoles and the molecular dipole moment. (a) HCN (b) I2 (c) NOarrow_forwardMethylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) Give values for the three bond angles indicated. (b) Indicate the most polar bond in the molecule. (c) Circle the shortest carbon-oxygen bond. (d) Circle the shortest carbon-carbon bond.arrow_forwardIndicate whether each of the following molecules is polar or nonpolar. The molecular geometry is given in parentheses. a. NF3 (trigonal pyramidal with N at the apex) b. NF2Cl (trigonal pyramidal with N at the apex) c. CS2 (linear with C in the center position) d. CHCl3 (tetrahedral with C in the center position)arrow_forward
- Use the VSEPR model to predict the bond angles around each central atom in the following Lewis structures (benzene rings are frequently pictured as hexagons, without the letter for the carbon atom at each vertex). Note that the drawings do not necessarily depict the bond angles correctly.arrow_forwardA student who missed this class needs to know how to predict the bond angles and shape of amolecule from looking at its bond-line representation. Write a concise but complete explanationfor this student.arrow_forwardAccording to the VSEPR model, what are the arrangements of two, three, four, five, and six valence-shell electron pairs about an atom?arrow_forward
- Indicate whether each of the following hypothetical triatomic molecules is polar or nonpolar. Assume that A, X, and Y have different electronegativities. a. a linear XAX molecule b. a linear XXA molecule c. an angular AXY molecule d. an angular XAY moleculearrow_forwardWhich of these molecules has a net dipole moment? For each of the polar molecules, indicate the direction of the dipole in the molecule. (a) nitrosyl fluoride, FNO (b) disulfur difluoride, S2F2arrow_forwardVitamin B6 is an organic compound whose deficiency in the human body can cause apathy, irritability, and an increased susceptibility to infections. Below is an incomplete Lewis structure for vitamin B6. Complete the Lewis structure and answer the following questions. Hint: Vitamin B6 can be classified as an organic compound (a compound based on carbon atoms). The majority of Lewis structures for simple organic compounds have all atoms with a formal charge of zero. Therefore, add lone pairs and multiple bonds to the structure below to give each atom a formal charge of zero. a. How many bonds and bonds exist in vitamin B6? b. Give approximate values for the bond angles marked a through g in the structure. c. How many carbon atoms are sp2 hybridized? d. How many carbon, oxygen, and nitrogen atoms are sp3 hybridized? e. Does vitamin B6 exhibit delocalized bonding? Explain.arrow_forward
- Write Lewis structures for these ions. Show all valence electrons and all formal charges. (a) Amide ion, NH2 (b) Bicarbonate ion, HCO3 (c) Carbonate ion, CO32 (d) Nitrate ion, NO3 (e) Formate ion, HCOO (f) Acetate ion, CH3COOarrow_forwardConsider the following compounds: CO2, SO2, KrF2, SO3, NF3, IF3, CF4, SF4, XeF4, PF5, IF5, and SCl6. These 12 compounds arc all examples of different molecular structures. Draw the Lewis structures for each and predict the molecular structure. Predict the bond angles and the polarity of each. (A polar molecule has a net dipole moment, while a nonpolar molecule docs not.) See Exercises 115 and 116 for the molecular structures based on the trigonal bipyramid and the octahedral geometries.arrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningWorld of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning