Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 12, Problem 33P
Draw structural formulas for all possible carbocations formed by the reaction of each
ch3
I
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Write down the common (not IUPAC) names of the organic molecules that would be released if this molecule were hydrolyzed:
CH2−O−C—(CH2);–CH=CH–CH2–CH=CH—(CH2)4—CH3
CH-O-C-(CH2)14-CH3
O
11
CH2−O−C— (CH2)14 — CH3
Separate each name with a comma. You will find useful information in the ALEKS Data resource.
1
010
Continue
O
a
X
000
Y
F8
F9
Submi
Name each alkyne.
a. CH=C-CH-CH3
CH3
b. CH3-C=C-CH-CH-CH,-CH,
CH3
CH3
c. CHEC-C-CH,-CH3
CH2
ČH,
CH3
d. CH;-C=C-CH-C-CH,
CH2 CH3
ČH3
Draw a structural formula for the alkene you would use to prepare the alcohol shown by hydroboration/oxidation.
CH3
CH3CHCH₂CH₂CH₂OH
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
• In cases where there is more than one answer, just draw one.
Chapter 12 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 12.3 - Prob. 12.1QCCh. 12.3 - Prob. 12.2QCCh. 12.3 - Problem 12-3 Write the IUPAC name for each...Ch. 12.3 - Problem 12-4 Draw structural formulas for the...Ch. 12.3 - Problem 12-5 How many stereoisomers are possible...Ch. 12.5 - Prob. 12.6QCCh. 12.5 - Problem 12-7 Propose a two-step mechanism for the...Ch. 12.5 - Prob. 12.8QCCh. 12.5 - Problem 12-9 Propose a three-step reaction...Ch. 12.5 - Prob. 12.10QC
Ch. 12.8 - Prob. 12.11QCCh. 12 - Prob. 1PCh. 12 - Answer true or false. Both ethylene and acetylene...Ch. 12 - 12-13 What is the difference in structure between...Ch. 12 - There are three compounds with the molecular...Ch. 12 - 12-15 Name and draw structural formulas for all...Ch. 12 - Prob. 6PCh. 12 - Draw a structural formula for at least one...Ch. 12 - Each carbon atom in ethane and in ethylene is...Ch. 12 - Prob. 9PCh. 12 - Prob. 10PCh. 12 - Prob. 11PCh. 12 - 12*22 Draw a structural formula for each compound....Ch. 12 - 12-23 Draw a structural formula for each compound....Ch. 12 - Prob. 14PCh. 12 - 12-25 Write the IUPAC name for each unsaturated...Ch. 12 - Explain why each name is incorrect and then write...Ch. 12 - 12-27 Explain why each name is incorrect and then...Ch. 12 - Prob. 18PCh. 12 - 12-29 Which of these alkenes show cis-trans...Ch. 12 - 12-30 Which of these alkenes shows cis-trans...Ch. 12 - 12-31 Cyclodecene exists as both cis and trans...Ch. 12 - Arachidonic acid is a naturally occurring C„o...Ch. 12 - Prob. 23PCh. 12 - If you examine the structural formulas for the...Ch. 12 - 12*35 For each molecule that shows eis-trans...Ch. 12 - Name and draw structural formulas for all...Ch. 12 - /3-Ocimene, a triene found in the fragrance of...Ch. 12 - Answer true or false. Alkenes and alkynes are...Ch. 12 - Prob. 29PCh. 12 - 12-40 Define alkene addition reaction. Write an...Ch. 12 - Prob. 31PCh. 12 - 12-42 Complete these equations.Ch. 12 - Draw structural formulas for all possible...Ch. 12 - Prob. 34PCh. 12 - 12-45 Draw a structural formula for the product of...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - 12-47 Draw a structural formula for an alkene with...Ch. 12 - Draw a structural formula for an alkene with the...Ch. 12 - Prob. 39PCh. 12 - 12-50 Draw the structural formula of an alkene...Ch. 12 - Prob. 41PCh. 12 - Prob. 42PCh. 12 - Following is the structural formula of...Ch. 12 - Propose an explanation for the following...Ch. 12 - There are nine alkenes with the molecular formula...Ch. 12 - Prob. 46PCh. 12 - 12-57 Hydrocarbon A, Cf,Hs, reacts with 2 moles of...Ch. 12 - 12-58 Show how to convert ethylene to these...Ch. 12 - 12-59 Show how to convert 1-butene to these...Ch. 12 - Prob. 50PCh. 12 - 12-61 (Chemical Connections 12A) What is one...Ch. 12 - Prob. 52PCh. 12 - Prob. 53PCh. 12 - 12-64 (Chemical Connections 120 What is the...Ch. 12 - (Chemical Connections 120 Assume that 1 X IO-12 g...Ch. 12 - Prob. 56PCh. 12 - Prob. 57PCh. 12 - Prob. 58PCh. 12 - Prob. 59PCh. 12 - Prob. 60PCh. 12 - Prob. 61PCh. 12 - Suppose you have unlabeled bottles of benzene and...Ch. 12 - Prob. 63PCh. 12 - Prob. 64PCh. 12 - Answer true or false. (a) Phenols and alcohols...Ch. 12 - Prob. 66PCh. 12 - Prob. 67PCh. 12 - Prob. 68PCh. 12 - Prob. 69PCh. 12 - 12-67 (Chemical Connections 12D ) In which isomer...Ch. 12 - Prob. 71PCh. 12 - Prob. 72PCh. 12 - Prob. 73PCh. 12 - Prob. 74PCh. 12 - Prob. 75PCh. 12 - Prob. 76PCh. 12 - Prob. 77PCh. 12 - Prob. 78PCh. 12 - Prob. 79PCh. 12 - Prob. 80PCh. 12 - Prob. 81PCh. 12 - Prob. 82PCh. 12 - Prob. 83PCh. 12 - Prob. 84PCh. 12 - Prob. 85PCh. 12 - Prob. 86PCh. 12 - Propose a structural formula for the product!s)...Ch. 12 - Prob. 88PCh. 12 - Draw the structural formula of an alkene that...Ch. 12 - 12-77 Show how to convert cyclopentene into these...Ch. 12 - Prob. 91PCh. 12 - Prob. 92PCh. 12 - Prob. 93PCh. 12 - Prob. 94PCh. 12 - Prob. 95PCh. 12 - In omega-3 fatty adds, the last carbon of the last...Ch. 12 - Prob. 97PCh. 12 - Prob. 98P
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- Draw a structural formula for the alkene you would use to prepare the alcohol shown by hydroboration/oxidation. H3C CH3 CH3CHCCH3 ОН You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one.arrow_forwardPyrethrins, such as jasmolin II (shown below), are a group of natural compounds that are synthesized by flowers of the genus Chrysanthemum (known as pyrethrum flowers) to act as insecticides. CH3 CH2=CH-CH. CH-C- -HCS 0-CH, CH,-C H2C- ČH, Which is not a functional group or structural feature in jasmolin II? cycloalkane carboxylic acid ester alkenearrow_forwardThe chemical reaction of 2-butene and HCl yields what product? O CH3CH₂CH₂CH3 O CI CH 3 CH 2 C HCH 3 CI CI I 1 CH3-CH-CH-CH3 CH3 I CH3 CHCH3 Cl I CH 3 C CH 2 CH 3 CH3 O Oarrow_forward
- 7. Which of the following structures have incorrect IUPAC names? If incorrect give the correct one. a. CH₂C=CCH₂CH(CH3)2 2-Methyl-4-hexyne CH₂CH₂ H CH₂CHCICH3 H trans-6-Chloro-3-heptene CH₂CH(CH₂)CH₂C=CCH₂CH(CH3)CH₂CH₂ 2-Ethyl-7-methyl-4-octynearrow_forwardWrite the IUPAC name of the product of this reaction: HBr CH2=C(CH3)2arrow_forwardName each compound in which the benzene ring is best treated as a substituent. CH3 a. CH3-CH-CH,-CH-CH,-CH–CH,-CH; CH,-CH3 b. CH,-CH-CH=CH-CH,-CH,–CH,-CH, c. CH3-C=C-CH-CH-CH-CH2-CH3 CH3 CH3arrow_forward
- AH° values obtained for a series of similar reactions are one set of experimental data used to determine the relative stability of alkenes. Explain how the following data suggest that cis-2-butene is more stable than 1-butene (Section 12.3A). CH2=CHCH,CH, + H2 CH;CH2CH2CH3 AH° =-127 kJ/mol 1-butene CH3 CH3 C=C + H2 CH3CH,CH,CHg AH° =-120 kJ/mol cis-2-butenearrow_forwardA. Complete and balance the following combustion reactions. Assume that each hydrocarbon is converted completely to carbon dioxide and water. 1. Propane + O2 → 2. Cyclohexane + 02→ 3.2-Methylpentane + O2 → B. Following are structural formulas and heats of combustion of acetaldehyde and ethylene oxide. Which of these compounds is the more stable? Explain. CH-CH H,C-CH2 Acetaldehyde -1164 kJ (-278.8 kcal)/mol Ethylene oxide -1264 kJ (-302.1 kcal)/molarrow_forwardDraw all the isomers that have molecular formula C5H11Br. a. Give the systematic name for each of the isomers. b. Give a common name for each isomer that has a common name. c. How many of the isomers are primary alkyl halides? d. How many of the isomers are secondary alkyl halides? e. How many of the isomers are tertiary alkyl halides?arrow_forward
- A student drew the structural diagram shown below. CH, 2 HHHHHHHH 1 H-C-C-C-C-C-C-C-C-H III HHHHHHHH 3 CH₂CH₂CH₂ oct-3-ene Compounds that Contain Eight Carbons 2,3-dimethylhex-2-ene I 5 CH₂CH₂ 6 2,3-dimethyl-1-propylcyclopropane 7 CH₂ CH₂ 4 3,3-dimethylhexane The compounds above that are isomers of the structural diagram that the student drew are numbered ______ '__—_ › andarrow_forwardCH,-C-CHCH, Classify each compound as an aldehyde or a ketone. Give the common name for each ketone. CH,CH,CH,-C-H CH,CH,CH,-C-CH,CH,CH, CH, CH;-C-CHCH, Name the following organic compound containing oxygen. CH, O CH, 3, | CH,CH-C-CHCH, || CH,CH,CH,-C-CH,CH, CH3 || CH,CH,CH,CH-Ĉ-H CH3 CH,CH,CH-C–Harrow_forwardClassify each of the following as either a substitution, elimination, or addition reaction. CH3-CH₂-CH2-CH3 Cr catalyst Δ CH3 HO-C-C-CH3 + NH3 CH3 CH3—CHO—CH3 + HO—CH3 OH CH3 CH3-CH-CH2-CH₂-Br DBN CH3 CH3 CH3-C=C-CH3 + H₂O. H* H* CH3–CH2–CH=CH2 + H2 H2N- CH3 -C-CH3 + H₂O CH3 CH3-CHO-CH3 + H2O O CH3 CH3 CH3-CH-CH=CH₂ + HBr CH3 CH3 CH3-C-CH-CH3 OH O substitution O elimination O addition O substitution O elimination O addition O substitution O elimination O addition O substitution O elimination O addition O substitution O elimination O addition X Sarrow_forward
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