Concept explainers
(a)
Interpretation:
The method by which
Concept introduction:
Alcohol can be prepared from an
When the
(b)
Interpretation:
The methods by which
Concept introduction:
Alcohol can be prepared from an alkene by addition reactions. These are the organic reactions in which two or more than two molecules combine to form a bigger product.
When the
(c)
Interpretation:
The methods by which
Concept introduction:
Alcohol can be prepared from an alkene by addition reactions. These are the organic reactions in which two or more than two molecules combine to form a bigger product.
When the
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EBK ORGANIC CHEMISTRY-PRINT COMPANION (
- Aldehydes and ketones react with one molecule of an alcohol to form compounds called hemiacetals, in which there is one hydroxyl group and one ether-like group. Reaction of a hemiacetal with a second molecule of alcohol gives an acetal and a molecule of water. We study this reaction in Chapter 16. Draw structural formulas for the hemiacetal and acetal formed from these reagents. The stoichiometry of each reaction is given in the problem.arrow_forwardList the following compounds in order of increasing water solubility: a.ethoxyethane b.propanoic acid c.pentane d.1 butanolarrow_forwardGive the structure of an alcohol that could be used to prepare each of the following compounds: a. b. c.arrow_forward
- Draw structural formulas for the alkene that gives each alcohol upon hydroboration-oxidation. (a) (b)arrow_forwardAnhydrous oxidations of primary alcohols can stop the oxidation at the aldehyde stage. A common reagent is Pyridinium chlorochromate (PCC). Draw the expected oxidation product of a primary alcohol with PCC.arrow_forwardWhich of the following reactions can be used to make the following alcohol? OH 1. LIAIH4, ether 2. H30* 1. OsO4 2. NaHSO3, H20 1. CH3CH2MgBr, ether H. 2. H3O*, H2O 1. Hg(OAc)2, H2O/THF 2. NABH4 MacBook Proarrow_forward
- Alcohols are really useful starting materials for chemical reactions, as they can be converted into many different organic compounds. For each of the following compounds tell me which alcohol you would need to use. The reaction I have in mind is a single reaction, not a multi step reaction process. Write out the name of the starting alcohol using proper IUPAC rules for naming. A) dipropyl ether B) cyclohexene C) 2,3-dinethylbutanal D) 2,2,4-trimethyl-3-hexanonearrow_forwardWhat reactions are needed to convert alcohol A to either alkyne B oralkyne C?arrow_forwardWrite the complete chemical reaction and correct chemical formula and structure of the following: 1. Autooxidation of benzaldehyde 2. reaction between acetic acid and ethanol 3. reaction between aspirin and sodium hydroxide 4. reaction of acetone with methanolarrow_forward
- Which of the following is not a physical property of alcohols or phenols? Select one: A. The solubilities of primary alcohols in water decrease with increasing molecular weight. B. Phenols are generally only slightly soluble in water. C. Due to hydrogen bonding, boiling points of alcohols are much higher than those of corresponding alkanes. D. The hydroxyl group of an alcohol is nonpolar.arrow_forwardWhat alcohol is produced from the reaction of acetone with the reagents, 1. CH3CH2M9B1/2. H2O? A. Primary alcohol B. Secondary Alcohol C. Tertiary Alcohol D. Allylalcoholarrow_forwardWhat product would result from the oxidation of each of the following alcohols? Using bond-line to write complete chemical reactions by providing all possible reagents. a. 2-pentenol + PCC → b. 3-ethylcyclopentanol + H2Cr2O7 →arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning