Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 12.SE, Problem 40AP
Interpretation Introduction

Interpretation:

The nature of the ketone has to be identified in Carvone.

Concept introduction:

Spectroscopy:

It is study of the interaction of matter and electromagnetic radiation, a continuum of different types of electromagnetic radiation each associated with a particular energy range makes up the electromagnetic spectrum.

IR frequency (cm-1):

It is the number of wave crests that pass by a given point in one second frequency has units of hertz (Hz).

Stretch vibrations:

It is a vibration occurring along the line of the bond a stretching vibration changes the bond length.

Bending vibrations:

It is a vibration that does not occur along the line of the bond, bending vibration changes the bond angle.

Given information:

The intense absorption at 1690cm-1 for Carvone.

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The functional groups in an organic compound can frequently be deduced from its infrared absorption spectrum. A compound containing no nitrogen exhibits strong, broad absorption across the 2500-3300 cm-1 region, accompanied by 2200 (w) and 1715 (s) cm-1bands.Relative absorption intensity: (s)=strong, (m)=medium, (w)=weak. What functional class(es) does the compound belong to? List only classes for which evidence is given here. Attach no significance to evidence not cited explicitly.Do not over-interpret exact absorption band positions. None of your inferences should depend on small differences like 10 to 20 cm-1. The functional class(es) of this compound is(are)fill in the blank 1.(Enter letters from the table below, in any order, with no spaces or commas.) a. alkane (List only if no other functional class applies.)   b. alkene h. amine c. terminal alkyne i. aldehyde or ketone d. internal alkyne j. carboxylic acid e. arene k. ester f. alcohol l. nitrile g. ether
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Chapter 12 Solutions

Organic Chemistry

Ch. 12.8 - Where might the following compound have IR...Ch. 12.SE - Prob. 12VCCh. 12.SE - Show the structures of the fragments you would...Ch. 12.SE - Propose structures for compounds that fit the...Ch. 12.SE - Write molecular formulas for compounds that show...Ch. 12.SE - Camphor, a saturated monoketone from the Asian...Ch. 12.SE - The nitrogen rule of mass spectrometry says that a...Ch. 12.SE - In light of the nitrogen rule mentioned in Problem...Ch. 12.SE - Nicotine is a diamino compound isolated from dried...Ch. 12.SE - The hormone cortisone contains C, H, and O, and...Ch. 12.SE - Halogenated compounds are particularly easy to...Ch. 12.SE - Prob. 22APCh. 12.SE - Propose structures for compounds that fit the...Ch. 12.SE - 2-Methylpentane (C6H14) has the mass spectrum...Ch. 12.SE - Assume that you are in a laboratory carrying out...Ch. 12.SE - What fragments might you expect in the mass...Ch. 12.SE - How might you use IR spectroscopy to distinguish...Ch. 12.SE - Would you expect two enantiomers such as...Ch. 12.SE - Would you expect two diastereomers such as meso-2,...Ch. 12.SE - Propose structures for compounds that meet the...Ch. 12.SE - How could you use infrared spectroscopy to...Ch. 12.SE - Prob. 32APCh. 12.SE - At what approximate positions might the following...Ch. 12.SE - How would you use infrared spectroscopy to...Ch. 12.SE - At what approximate positions might the following...Ch. 12.SE - Assume that you are carrying out the dehydration...Ch. 12.SE - Assume that you are carrying out the base-induced...Ch. 12.SE - Prob. 38APCh. 12.SE - Carvone is an unsaturated ketone responsible for...Ch. 12.SE - Prob. 40APCh. 12.SE - The mass spectrum (a) and the infrared spectrum...Ch. 12.SE - The mass spectrum (a) and the infrared spectrum...Ch. 12.SE - Propose structures for compounds that meet the...Ch. 12.SE - 4-Methyl-2-pentanone and 3-methylpentanal are...Ch. 12.SE - Grignard reagents undergo a general and very...Ch. 12.SE - Ketones undergo a reduction when treated with...Ch. 12.SE - Nitriles, R–=C≡N, undergo a hydrolysis...Ch. 12.SE - The infrared spectrum of the compound with the...Ch. 12.SE - The infrared spectrum of the compound with the...Ch. 12.SE - Prob. 50AP
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