Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 23, Problem 23.48SP

(a)

Interpretation Introduction

To determine: The name of the given aldose.

Interpretation: The name of the given aldose is to be stated.

Concept introduction: The two diastereomeric sugars which differ only in the configuration at a single asymmetric carbon atom are known as epimers. Aldose is a monosaccharide which contains an aldehyde carbonyl group.

(b)

Interpretation Introduction

To determine: The name of the given aldose.

Interpretation: The name of the given aldose is to be stated.

Concept introduction: The two diastereomeric sugars which differ only in the configuration at a single asymmetric carbon atom are known as epimers. Aldose is a monosaccharide which contains an aldehyde carbonyl group.

(c)

Interpretation Introduction

To determine: The name of the given aldose.

Interpretation: The name of the given aldose is to be stated.

Concept introduction: The two diastereomeric sugars which differ only in the configuration at a single asymmetric carbon atom are known as epimers. Aldose is a monosaccharide which contains an aldehyde carbonyl group.

(d)

Interpretation Introduction

To determine: The name of the given aldose.

Interpretation: The name of the given aldose is to be stated.

Concept introduction: The two diastereomeric sugars which differ only in the configuration at a single asymmetric carbon atom are known as epimers. Aldose is a monosaccharide which contains an aldehyde carbonyl group.

(e)

Interpretation Introduction

To determine: The name of the given aldose.

Interpretation: The name of the given aldose is to be stated.

Concept introduction: The two diastereomeric sugars which differ only in the configuration at a single asymmetric carbon atom are known as epimers. Aldose is a monosaccharide which contains an aldehyde carbonyl group.

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2. Draw the two aldohexoses and one ketohexose that can be derived from the enol shown below. HC OH но H- HO- HO ČH,OH 3. Classify the following monosaccharides as reducing and nonreducing sugars. CH,OH CH,OH CH,OH OH он но - HO- OH OH HO он OH OH ČH,OH II III 4. Identify and name the glycosidic bond in the structure shown below. CH,OH OH OH он
Which of the following best describes the disaccharide shown here? HO. он, но OH OH HO A. a-1,4' glycoside of D-glucose and D-galactose B. B-1,3' glycoside of D-glucose and D-galactose C. a-1,4' glycoside of D-galactose and D-glucose D. B-1,4' glycoside of D-gulose and D-galactose E. a-1,3' glycoside of D-allose and D-glucose F. a-1,3' glycoside of D-idose and D-idose G. a-1,3' glycoside of D-altrose and D-galactose H. B-1,3' glycoside of D-altrose and D-galactose
7. Why are protecting groups needed in this reaction and what is the purpose of CH2C12? Can you explain this reaction to me? I understand intermediate 10 will be a disaccharide. Bno Bno o co, Bno OAc NH TMSOTI (1,2)-linked tetramannoside 10 CH,Clz Bno. он Bno o Bno ROAI

Chapter 23 Solutions

Organic Chemistry (9th Edition)

Ch. 23.4 - Prob. 23.11PCh. 23.5 - Prob. 23.12PCh. 23.5 - Prob. 23.13PCh. 23.6 - Prob. 23.14PCh. 23.6 - Prob. 23.15PCh. 23.7 - Prob. 23.16PCh. 23.7 - Prob. 23.17PCh. 23.7 - Two sugars, A and B, are known to be glucose and...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Prob. 23.20PCh. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22PCh. 23.8 - Prob. 23.23PCh. 23.8 - Prob. 23.24PCh. 23.9 - a. Show the product that results when fructose is...Ch. 23.9 - Prob. 23.26PCh. 23.9 - Prob. 23.27PCh. 23.9 - Prob. 23.28PCh. 23.10 - Prob. 23.29PCh. 23.10 - Prob. 23.30PCh. 23.10 - Prob. 23.31PCh. 23.11 - Prob. 23.32PCh. 23.11 - The Wohl degradation, an alternative to the Ruff...Ch. 23.11 - Prob. 23.34PCh. 23.11 - Prob. 23.35PCh. 23.12A - Prob. 23.36PCh. 23.12A - Give an equation to show the reduction of Tollens...Ch. 23.12A - Prob. 23.38PCh. 23.12B - Prob. 23.39PCh. 23.12C - Prob. 23.40PCh. 23.12C - Prob. 23.41PCh. 23.13A - Prob. 23.42PCh. 23.15 - Cytosine, uracil, and guanine have tautomeric...Ch. 23.15 - a. An aliphatic aminoglycoside is relatively...Ch. 23.16C - Prob. 23.45PCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - Prob. 23.49SPCh. 23 - Prob. 23.50SPCh. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw the structure of a four-residue segment of...Ch. 23 - Retroviruses like HIV, the pathogen responsible...Ch. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SP
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