Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 23.3C, Problem 23.6P

(a)

Interpretation Introduction

Interpretation:

The structure of Dallose, the C3 epimer of Dglucose is to be drawn.

Concept introduction:

The isomers that differ in configuration about a carbon that is asymmetric in nature are known as epimers.

(b)

Interpretation Introduction

Interpretation:

The structure of Dtalose, the C2 epimer of Dgalactose is to be drawn.

Concept introduction:

The isomers that differ in configuration about the carbon that is asymmetric in nature are known as epimers.

(c)

Interpretation Introduction

Interpretation:

The structure of Didose, the C3 epimer of Dtalose and its comparison with the Figure 233 is to be stated.

Concept introduction:

The isomers that differ in configuration about the carbon that is asymmetric in nature are known as epimers.

(d)

Interpretation Introduction

Interpretation:

The structure of C4 “epimer” of Dxylose and the name of the L-series sugar formed is to be stated.

Concept introduction:

The isomers that differ in configuration about one the carbon that is asymmetric in nature are known as epimers.

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2. Draw the two aldohexoses and one ketohexose that can be derived from the enol shown below. HC OH но H- HO- HO ČH,OH 3. Classify the following monosaccharides as reducing and nonreducing sugars. CH,OH CH,OH CH,OH OH он но - HO- OH OH HO он OH OH ČH,OH II III 4. Identify and name the glycosidic bond in the structure shown below. CH,OH OH OH он
Which of the following best describes the disaccharide shown here? HO. он, но OH OH HO A. a-1,4' glycoside of D-glucose and D-galactose B. B-1,3' glycoside of D-glucose and D-galactose C. a-1,4' glycoside of D-galactose and D-glucose D. B-1,4' glycoside of D-gulose and D-galactose E. a-1,3' glycoside of D-allose and D-glucose F. a-1,3' glycoside of D-idose and D-idose G. a-1,3' glycoside of D-altrose and D-galactose H. B-1,3' glycoside of D-altrose and D-galactose
Observe carefully the structure below and choose the correct answer. Note "a through e ndicate carbon positions of this monosaccharide. OH н но HỌ HOH,C\ CH.OH ÕH H The structure shown in the figure above represents a A. glucopyranose B. ribofuranose C. myo-inositol D. fructofuranose O E. glucofuranose

Chapter 23 Solutions

Organic Chemistry (9th Edition)

Ch. 23.4 - Prob. 23.11PCh. 23.5 - Prob. 23.12PCh. 23.5 - Prob. 23.13PCh. 23.6 - Prob. 23.14PCh. 23.6 - Prob. 23.15PCh. 23.7 - Prob. 23.16PCh. 23.7 - Prob. 23.17PCh. 23.7 - Two sugars, A and B, are known to be glucose and...Ch. 23.7 - Prob. 23.19PCh. 23.8 - Prob. 23.20PCh. 23.8 - Prob. 23.21PCh. 23.8 - Prob. 23.22PCh. 23.8 - Prob. 23.23PCh. 23.8 - Prob. 23.24PCh. 23.9 - a. Show the product that results when fructose is...Ch. 23.9 - Prob. 23.26PCh. 23.9 - Prob. 23.27PCh. 23.9 - Prob. 23.28PCh. 23.10 - Prob. 23.29PCh. 23.10 - Prob. 23.30PCh. 23.10 - Prob. 23.31PCh. 23.11 - Prob. 23.32PCh. 23.11 - The Wohl degradation, an alternative to the Ruff...Ch. 23.11 - Prob. 23.34PCh. 23.11 - Prob. 23.35PCh. 23.12A - Prob. 23.36PCh. 23.12A - Give an equation to show the reduction of Tollens...Ch. 23.12A - Prob. 23.38PCh. 23.12B - Prob. 23.39PCh. 23.12C - Prob. 23.40PCh. 23.12C - Prob. 23.41PCh. 23.13A - Prob. 23.42PCh. 23.15 - Cytosine, uracil, and guanine have tautomeric...Ch. 23.15 - a. An aliphatic aminoglycoside is relatively...Ch. 23.16C - Prob. 23.45PCh. 23 - Prob. 23.46SPCh. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - Prob. 23.49SPCh. 23 - Prob. 23.50SPCh. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Prob. 23.59SPCh. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Draw the structure of a four-residue segment of...Ch. 23 - Retroviruses like HIV, the pathogen responsible...Ch. 23 - Prob. 23.66SPCh. 23 - Prob. 23.67SP
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