Organic Chemistry
Organic Chemistry
5th Edition
ISBN: 9780078021558
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 3, Problem 3.6P
Interpretation Introduction

(a)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is RNH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

Interpretation Introduction

(b)

Interpretation: The primary, secondary or tertiary amine in the given compound is to be classified.

Concept introduction: Amines are nitrogen-containing organic compounds. The general formula of amines is RNH2. Amines can be classified as primary amine, secondary amine, and tertiary amine. In Primary amines, one of the hydrogen atoms of ammonia is replaced by alkyl or aryl group.

In secondary amines, two of the hydrogen atoms of ammonia are replaced by alkyl or aryl group.

In tertiary amines, all hydrogen atoms of ammonia are replaced by alkyl or aryl group.

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1. Which statement best described the ability of amines to hydrogen bond?       A. Primary, secondary and tertiary amines can all hydrogen bond with molecules identical to themselves.       B. Primary and secondary amines can hydrogen bond with molecules identical to themselves, but tertiary amines cannot.       C. Only primary amines can hydrogen bond with molecules identical to themselves. Secondary and tertiary amines cannot.       D. Primary, secondary and tertiary amines cannot hydrogen bond with molecules identical to themselves, but the can hydrogen bond with water.
V. Classify each amine as 1', 2 or 3'. Give the IUPAC name for each amine. CH3 a. CH3CHCH,CH2NHCH3 b. CH3-C-CH,NH2 ČH3 ČH3
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Chapter 3 Solutions

Organic Chemistry

Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Which compound in each pair has the higher boiling...Ch. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.16PCh. 3 - Which compounds are water soluble? a. b. c.Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Problem 3.23 (a) What types of intermolecular...Ch. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - Prob. 3.28PCh. 3 - 3.29 Identify the functional groups in the...Ch. 3 - Prob. 3.30PCh. 3 - 3.31 For each alkane: (a) classify each carbon...Ch. 3 - 3.32 Identify the functional groups in each...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - 3.34 (a)Identify the functional groups in...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.36PCh. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - 3.41 Rank the compounds in each group in order of...Ch. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.43PCh. 3 - 3.44 Rank the following compounds in order of...Ch. 3 - Prob. 3.45PCh. 3 - 3.46 Rank the following compounds in order of...Ch. 3 - 3.47 Which of the following molecules can hydrogen...Ch. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.49PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - 3.53 THC is the active component in marijuana, and...Ch. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - 3.56 Label the electrophilic and nucleophilic...Ch. 3 - 3.57 By using only electron density arguments,...Ch. 3 - 3.58 The composition of a cell membrane is not...Ch. 3 - Prob. 3.59PCh. 3 - 3.60 Quinapril (trade name Accupril) is a drug...Ch. 3 - 3.61 Answer each question about oxycodone, a...Ch. 3 - Prob. 3.62PCh. 3 - Prob. 3.63PCh. 3 - 3.64 Explain why A is less water soluble than B,...Ch. 3 - 3.65 Recall from section 1.10B that there is...
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