All the possible monochlorinated derivatives of given compounds. Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn. Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

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Answer 1

Question

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

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10. In free-radical substitution reaction of alkanes with halogens under uv light, A. the photolytic breaking of the halogen is the rate determining step. B. the abstraction of hydrogen from alkane by the halogen radical is the rate determining step C. the formation of alkylradical is the rate determining step. D. the formation of halogen radical is the rate determining step. 11. Which of the following processes could be the termination step in free radical substitution reaction? A. C₂H6 ---→ 2CH3 B. C₂H6 +H. --→ H₂ + C₂H5 C. CH3 + CH3 --→ C₂H₂ D. C₂H5 --→ C₂H4 + H 12. Which of the following is the most stable carbonium ion intermediate? A. primary carbonium ion B. secondary carbonium ion C. tertiary carbonium ion D. allyl carbonium ion

In the addition reactions of alkynes, the reagents undergo transformation to form first. a. a nucleophile b. an electrophile c. a carbocation d. a radical

2-Methyl-2-butene reacts with HBr in the presence of peroxide to give a. a secondary alkyl bromide. b. a primary alkyl bromide. c. a tertiary alkyl bromide. d. a vicinal dibromide.

Answer 2

Question

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

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Answer 3

Question

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

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Answer 4

Question

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

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Answer 5

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

Answer 6

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

Answer 7

Chapter 4, Problem 4.43SP

(1)

Interpretation Introduction

To determine: All the possible monochlorinated derivatives of given compounds.

Interpretation: All the possible monochlorinated derivatives of given compounds are to be drawn.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

Answer 8

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

Answer 9

(2)

Interpretation Introduction

To determine: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not and if the reaction would give one major product.

Interpretation: If the free-radical chlorination is a reasonable way to make monochlorinated derivatives of given compounds or not is to be predicted and if the reaction would give one major product is to be stated.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light.

Answer 10

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

Answer 11

(3)

Interpretation Introduction

To determine: The monobrominated derivative of given compounds that could be formed in good yield.

Interpretation: The monobrominated derivative of given compounds that could be formed in good yield is to be predicted.

Concept introduction: The chemical reaction which proceeds through the formation of radicals is known as chain reaction. It involves three steps, initiation, propagation and termination. Generally, the initiation step occurs in the presence of light. The order of stability of free radical at carbon atom is 3°>2°>1°.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 4.3A - Draw Lewis structures for the following free...Ch. 4.3B - a. Write the propagation steps leading to the...Ch. 4.3C - Prob. 4.3P Ch. 4.3C - Prob. 4.4P Ch. 4.4 - The following reaction has a value of G =...Ch. 4.4 - Under base-catalyzed conditions two molecules of...Ch. 4.5B - When ethene is mixed with hydrogen in the presence...Ch. 4.5B - For each reaction, estimate whether S for the...Ch. 4.7 - a. Propose a mechanism for the free radical...Ch. 4.7 - a. Using bond-dissociation enthalpies from...

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