Chemistry: The Molecular Science
Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 9, Problem 97QRT
Interpretation Introduction

Interpretation:

The total heat energy transferred to cool a 10.0gCCl2F2 from 40C to 40C has to be calculated.

Concept Introduction:

Calculation of heat energy:

When both the phases are same means a transition is taking place within the same phase like between liquid to liquid, ΔH0=m×s×Δθ

Where, m= mass of substance, s= Specific heat of substance in a particular phase and Δθ= Temperature difference.

When two phases are different means a transition is taking place between two different phases like between solid to liquid, ΔH0=n×ΔfusorvapH0

Where, n= No. of moles of substance , ΔfusH0= Fusion enthalpy of a substance in its solid phase and ΔvapH0= enthalpy of vaporization of a substance in its liquid phase.

Expert Solution & Answer
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Answer to Problem 97QRT

The total heat energy evolved to cool a 10.0gCCl2F2 from 40C to 40C is 2.174kJ.

Explanation of Solution

Given data:

The specific heat capacities of gas and liquid are .61Jg1C1 and 0.97Jg1C1 respectively. Its normal boiling point is 30C.  The vaporization enthalpy is 165Jg1.

  1. 1. Cool it from 40oC to its boiling point -30oC

The heat energy evolved during the cooling of 10g of CCl2F2 can be calculated as given below.

  ΔH0=m×s×Δθ=(10g)(.61Jg1C1)[(30C)(40C)]=427J.

Where, m= mass of CCl2F2, s= Specific heat of gas and Δθ= Temperature difference.

  1. 2. Condensation of the gas to liquid at -30oC

The heat energy evolved for this process can be calculated as given below.

  ΔH0=m×ΔvapH0=10g×165Jg=1650J.

  1. 3. Cool it further from -30oC to -40oC

The heat energy evolved for this process can be calculated as given below.

  ΔH0=m×s×Δθ=(10g)(0.97Jg1C1)[(40C)(30C)]=97J.

Now, the total heat energy transferred to cool a 10.0gCCl2F2 from 40C to 40C is the sum total of all the heat energies required for each transition:

  ΔH=427J1650J97J=2174J=(2174J)(1kJ1000J)=2.174kJ.

Therefore, the total heat energy evolved to cool a 10.0gCCl2F2 from 40C to 40C is 2.174kJ.

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Chapter 9 Solutions

Chemistry: The Molecular Science

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