Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 11.7B, Problem 11.14P
Show how you would use a simple chemical test to distinguish between the following pairs of compounds. Tell what you would observe with each compound.
- a. isopropyl alcohol and tert-butyl alcohol
- b. isopropyl alcohol and butan-2-one, CH3COCH2CH3
- c. hexan-1-ol and cyclohexanol
- d. allyl alcohol and propan-1-ol
- e. butan-2-one and tert-butyl alcohol
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
CH2
H3C
H3C
COOH
Reagents
e. PB13
f. NaCN then H3O*
g. NBS, CCI4
h. CrO3, H2SO4
а.
HBr
b. Mg, ether
c. CO2, ether then H3O*
d. BH3, THF then H2O2, OH"
Reagents
a. C6H5CHO
b. NaOH, ethanol
h. BrCH2CH=CH2
i.
Na* OEt, ethanol
j. Br2, H*
k. K* t-BuO
c. Pyrrolidine, cat. H*
d. H2C=CHCN
e. H3O*
f.
I. CH2(CO2ET)2
-CH2CH2CN
LDA
m. heat
g. ELOC(=0)CO2ET
Select reagents from the table to synthesize this compound from cyclopentanone.
Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda).
F.
OH
1. Write the IUPAC names for these alcohols.
A. CH,OHCH(CHa)CH,OH
В.
CH3
G.
CICH2CHCHCH3
но
OH
Н.
C.
но
OH
CI
1.
HO
D.
OH
J.
ÇH3
он
CHCHCHCH(CHз)2
E.
CH2CH3
OH
K.
OH
Br
CH3
OH
Page 1
Chapter 11 Solutions
Organic Chemistry (9th Edition)
Ch. 11.1 - Prob. 11.1PCh. 11.2C - Prob. 11.2PCh. 11.3 - Prob. 11.3PCh. 11.3 - Prob. 11.4PCh. 11.3 - Prob. 11.5PCh. 11.3 - Suggest the most appropriate method for each of...Ch. 11.4 - A chronic alcoholic requires a much larger dose of...Ch. 11.4 - Unlike ethylene glycol, propylene glycol...Ch. 11.5 - Predict the major products of the following...Ch. 11.5 - Show how you would convert propan-1-ol to the...
Ch. 11.6 - Predict the products of the following reactions....Ch. 11.7A - Propose a mechanism for the reaction of a....Ch. 11.7B - Prob. 11.13PCh. 11.7B - Show how you would use a simple chemical test to...Ch. 11.7C - Neopentyl alcohol, (CH3)3CCH2OH, reacts with...Ch. 11.7C - Prob. 11.16PCh. 11.7C - When cis-2-methylcyclohexanol reacts with the...Ch. 11.8 - Prob. 11.18PCh. 11.9 - Prob. 11.19PCh. 11.9 - Prob. 11.20PCh. 11.9 - Prob. 11.21PCh. 11.10A - Prob. 11.22PCh. 11.10A - Some alcohols undergo rearrangement or other...Ch. 11.10B - Prob. 11.24PCh. 11.10B - Explain why the acid-catalyzed condensation is a...Ch. 11.10B - Prob. 11.26PCh. 11.10B - When the following substituted cycloheptanol...Ch. 11.11A - Prob. 11.28PCh. 11.11A - Prob. 11.29PCh. 11.11B - Predict the products formed by periodic acid...Ch. 11.12 - Prob. 11.31PCh. 11.13A - Prob. 11.32PCh. 11.14 - Prob. 11.33PCh. 11.14 - a. Show how ethanol and cyclohexanol may be used...Ch. 11.14 - Prob. 11.35PCh. 11.14 - Phenols (pKa 10) are more acidic than other...Ch. 11.14 - To practice working through the early parts of a...Ch. 11.14 - Prob. 11.38PCh. 11 - Predict the major products of the following...Ch. 11 - Show how you would convert 2-methylcyclopentanol...Ch. 11 - In each case, show how you would synthesize the...Ch. 11 - Prob. 11.42SPCh. 11 - Prob. 11.43SPCh. 11 - Prob. 11.44SPCh. 11 - Both cis- and trans-2-methylcyclohexanol undergo...Ch. 11 - Prob. 11.46SPCh. 11 - Prob. 11.47SPCh. 11 - Show how you would make each compound, beginning...Ch. 11 - Predict the major products (including...Ch. 11 - Show how you would use simple chemical tests to...Ch. 11 - The compound shown below has three different types...Ch. 11 - Prob. 11.52SPCh. 11 - Prob. 11.53SPCh. 11 - Prob. 11.54SPCh. 11 - Prob. 11.55SPCh. 11 - Show how you would synthesize the following...Ch. 11 - Show how you would synthesize the following...Ch. 11 - The following pseudo-syntheses (guaranteed not to...Ch. 11 - Two unknowns, X and Y, both having the molecular...Ch. 11 - The Williamson ether synthesis involves the...Ch. 11 - Prob. 11.61SPCh. 11 - Prob. 11.62SPCh. 11 - Alcohols combine with ketones and aldehydes to...Ch. 11 - Prob. 11.64SPCh. 11 - Prob. 11.65SPCh. 11 - Prob. 11.66SP
Additional Science Textbook Solutions
Find more solutions based on key concepts
The method to determine the volume of a powered solid, liquid and a rock needs to be determined. Concept introd...
Living by Chemistry
During the early part of the 20th century, sulfanilamide (an antibacterial drug) was only administered by injec...
Elementary Principles of Chemical Processes, Binder Ready Version
4. 38 Strontium has four naturally occurring isotopes, with mass numbers 84, 86, 87, arid 88.
a. Write the atom...
General, Organic, and Biological Chemistry: Structures of Life (5th Edition)
Consider a sample of ideal gas initially in a volume V at temperature T and pressure P. Does the entropy of thi...
General Chemistry: Principles and Modern Applications (11th Edition)
Practice Exercise 1
Which of the following factors determines the size of an atom? a. the volume of the nucleus...
Chemistry: The Central Science (13th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Label each functional group as an alcohol, ether, acetal, or hemiacetal. LOCH3 a. OCH3 (select) OH b. CH3-C-OCH2CH,CH3 CH3 (select) с. `OCH,CH,CH3 (select) d. OCH,CH,CH3 (select) (select) two ethers hemiacetal acetal alcohol and ether alcohol etherarrow_forwardShow how to prepare each compound from 2-methyl- 1- propanol. a. 2- methylpropene b. 2- methyl- 2- propanol c. 2- methylpropanoic acid (CH3)2CHCOOHarrow_forward3. Predict the major products of the following reactions. Include stereochemistry where appropriate.arrow_forward
- What is the IUPAC name for the following compounds in the image. Please explain if it is cis or trans and illustrate the compounds in their corresponding drawings. For compound 1: a. cis-4-isopropylcyclohexanol b. trans-4-hydroxy-1-isopropylcyclohexane c. trans-4-isopropylcyclohexanol d. cis-4-hydroxy-1-isopropylcyclohexane e. p-isopropylcyclohexanol f. cis-1-hydroxy-4-isopropylcyclohexane For compound 2: a. 3-ethylpent-3-ol b. 2,2-diethylbut-1-ol c. 2-ethylpent-3-ol d. 2-ethylpent-2-olarrow_forward16. Identify each compound as an a cohol, a phenol, or an ether. Classify any alcohols as primary (1"), secondary (2), or tertiary (3"). a. CH,CH,CH,OH CH,CHCH, b. CHO C. CH CHOCH, CH, d.arrow_forwardWhat is C terminal amino adid of the peptide below? HO N. HO H2N N. N. Select one: a. H,N-CH- O H,N-CH-C OHarrow_forward
- CHOOSE THE LETTER OF THE CORRECT ANSWER IN EACH NUMBER. 1. The delighted odor of melted butter is attributed to this four-carbon dione. What could be the IUPAC NAME of this ketone? a. Butanone b. Pentanedione c. Hexanone d. Butanedione 2. Carbocation stability is important in reaction mechanisms involving alcohols. Based on the general structure of alcohols, rank the carbocation stability of alcohols (increasing trend) if a central carbon is the point of reference. a. Tertiary alcohol > Primary alcohol > Secondary alcohol b. Primary alcohol > Secondary alcohol > Tertiary alcohol c. Secondary alcohol > Tertiary alcohol > Primary alcohol d. Tertiary alcohol > Secondary alcohol > Primary alcohol 3. Which type of alcohol generally exhibits a higher dipole moment relative to linear alcohol? a. Cyclic alkyl alcohol b. Allylic alcohol c.Tertiary alcohol d. Secondary alcoholarrow_forwardReagents a. CeHsCHO b. NaOH, ethanol c. Pyrrolidine, cat. H* d. H2C=CHCN e. H30* f. LDA g. ELOC(=0)CO,Et h. BRCH2CH=CH2 Na* OEt, ethanol j. Br2, H* k. K* t-BuO 1. CH2(CO2Et)2 m. heat Select reagents from the table to synthesize this compound from cyclopentanone. Enter the letters of the chosen reagents, in the order that you wish to use them, without spaces or punctuation (i.e. geda). Submit Answer Try Another Version 1 Item attempt remainingarrow_forwardList the products of each alcohol reaction. CH3 H,SO4 a. CH,-C-OH CH, NazCr0, b. CH3-CH-CH,-CH;-OH c. CH-CH-OH +HCI - CH3 d. CH3-CH-CH2-OH + Naarrow_forward
- Which of the following reactions can be used to make the following alcohol? OH 1. LIAIH4, ether 2. H30* 1. OsO4 2. NaHSO3, H20 1. CH3CH2MgBr, ether H. 2. H3O*, H2O 1. Hg(OAc)2, H2O/THF 2. NABH4 MacBook Proarrow_forwardWhich alcohol should be least soluble in a nonpolar solvent such as hexane, C,H14? СH CH-СH СH,CH-ОН b. CHCH,OH c. CH,CH2CH2OH d. CH,CH,CH.CН-ОН a.arrow_forward1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
Chemistry for Today: General, Organic, and Bioche...
Chemistry
ISBN:9781305960060
Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher:Cengage Learning
How to Design a Total Synthesis; Author: Chemistry Unleashed;https://www.youtube.com/watch?v=9jRfAJJO7mM;License: Standard YouTube License, CC-BY