Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
Question
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Chapter 11.SE, Problem 21VC
Interpretation Introduction

a)

Interpretation:

The expected product between the alkyl halide CH3CH2Cl+Na+SCH3- and NaOH is interpreted.

Expert Solution
Check Mark

Answer to Problem 21VC

The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.

The product is CH3CH2SCH3, CH3CH2OH.

Here the leaving group is Cl.

The nucleophile is SCH3-,OH.

Hence it undergoes SN2 reaction.

Explanation of Solution

The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.

The product is CH3CH2SCH3, CH3CH2OH.

Here the leaving group is Cl.

The nucleophile is SCH3-,OH.

Hence it undergoes SN2 reaction.

Conclusion

The ethyl chloride undergoes SN2 reaction with Na+SCH3- and NaOH to yield a product.

The product is CH3CH2SCH3, CH3CH2OH.

Here the leaving group is Cl.

The nucleophile is SCH3-,OH.

Hence it undergoes SN2 reaction.

Interpretation Introduction

b)

Interpretation:

The expected product between the alkyl halide CH3CH2Cl+Na+SCH3- and NaOH is interpreted.

Expert Solution
Check Mark

Answer to Problem 21VC

The alkyl halide undergoes SN1 reaction with Na+SCH3- to yield a SCH3 Substituited product.

The product is shown in the reaction.

In this reaction leaving group is Cl, the nucleophile is SCH3-

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  1

Explanation of Solution

The alkyl halide undergoes E1 reaction with NaOH to yield a alkene product.

The product is shown here

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  2

Conclusion

The alkyl halide undergoes SN1reaction with Na+SCH3- to yield a SCH3 Substituited product.

The product is shown in the reaction.

In this reaction leaving group is Cl, the nucleophile is SCH3-

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  3

Interpretation Introduction

c)

Interpretation:

The expected product between the alkyl halide CH3CH2Cl+Na+SCH3- and NaOH is interpreted.

Expert Solution
Check Mark

Answer to Problem 21VC

The benzylchloride undergoes SN1 reaction with Na+SCH3- to yield a product.

The product is shown here.

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  4

Here the leaving group is Cl.

The nucleophile is SCH3-Hence it undergoes SN1 reaction.

Explanation of Solution

The benzylchloride undergoes E1 reaction with NaOH to yield a product.

The product is shown here

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  5

Conclusion

The benzylchloride undergoes SN1 reaction with Na+SCH3- to yield a product.

The product is shown here.

Organic Chemistry, Chapter 11.SE, Problem 21VC , additional homework tip  6

Here the leaving group is Cl.

The nucleophile is SCH3- Hence it undergoes SN1 reaction.

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Chapter 11 Solutions

Organic Chemistry

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