Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 13.3, Problem 13.4P

(a)

Interpretation Introduction

Interpretation:

From the condensed structures for 2,3-dimethyl-2-pentene whether cis-trans isomers exist or not has to be given. And if it exists, both the isomers has to be drawn.

Concept Introduction:

Condensed structures: A condensed structures only shows the total number of atoms but not bonds exist between the atoms. The vertical and horizontal line which represents bonding all should be omitted.

Line structure: In organic compounds, the series of atoms in the compound are bonded together which shown by drawing a line between them. End of line segment represents carbon

Predicting cis-trans isomers:

In general, the alkene can exist as cis or trans isomer only if the two substituents on each carbon are not equal. Like,

Fundamentals of General, Organic, and Biological Chemistry (8th Edition), Chapter 13.3, Problem 13.4P

Cis-isomer: In cis-configuration, the two bulkier substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two bulkier substituents of the double bond are on the opposite side.

(b)

Interpretation Introduction

Interpretation:

From the both condensed and line structures for 2-Methyl-2-hexene whether cis-trans isomers exist or not has to be given. And if it exists, both the isomers has to be drawn.

Concept Introduction:

Condensed structures: A condensed structures only shows the total number of atoms but not bonds exist between the atoms. The vertical and horizontal line which represents bonding all should be omitted.

Line structure: In organic compounds, the series of atoms in the compound are bonded together which shown by drawing a line between them. End of line segment represents carbon

Cis-isomer: In cis-configuration, the two bulkier substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two bulkier substituents of the double bond are on the opposite side.

(c)

Interpretation Introduction

Interpretation:

From the line structures for 2-hexene whether cis-trans isomers exist or not has to be given. And if it exists, both the isomers has to be drawn.

Concept Introduction:

Condensed structures: A condensed structures only shows the total number of atoms but not bonds exist between the atoms. The vertical and horizontal line which represents bonding all should be omitted.

Line structure: In organic compounds, the series of atoms in the compound are bonded together which shown by drawing a line between them. End of line segment represents carbon

Cis-isomer: In cis-configuration, the two bulkier substituents of the double bond are on the same side.

Trans-isomer: In trans-configuration, the two bulkier substituents of the double bond are on the opposite side.

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Chapter 13 Solutions

Fundamentals of General, Organic, and Biological Chemistry (8th Edition)

Ch. 13.5 - Prob. 13.3CIAPCh. 13.6 - Prob. 13.9PCh. 13.6 - Prob. 13.10PCh. 13.6 - Prob. 13.11PCh. 13.6 - Prob. 13.12PCh. 13.6 - Prob. 13.13PCh. 13.6 - Prob. 13.14KCPCh. 13.6 - Prob. 13.1MRPCh. 13.6 - Prob. 13.2MRPCh. 13.6 - Prob. 13.3MRPCh. 13.7 - Prob. 13.15PCh. 13.7 - Prob. 13.16PCh. 13.8 - Prob. 13.17PCh. 13.8 - Polychlorotrifluoroethylene (PCTFE (Kel-F)) is a...Ch. 13.9 - Prob. 13.19PCh. 13.9 - Prob. 13.20PCh. 13.9 - Prob. 13.21KCPCh. 13.10 - What products will be formed when toluene is...Ch. 13.10 - Prob. 13.23PCh. 13.10 - Prob. 13.4CIAPCh. 13.10 - Prob. 13.5CIAPCh. 13.10 - Prob. 13.6CIAPCh. 13 - Prob. 13.24UKCCh. 13 - Prob. 13.25UKCCh. 13 - Prob. 13.26UKCCh. 13 - Draw the product from reaction of the following...Ch. 13 - Prob. 13.28UKCCh. 13 - Prob. 13.29UKCCh. 13 - Prob. 13.30APCh. 13 - Prob. 13.31APCh. 13 - What family-name endings are used for alkenes,...Ch. 13 - Prob. 13.33APCh. 13 - Prob. 13.34APCh. 13 - Write structural formulas for compounds that meet...Ch. 13 - Prob. 13.36APCh. 13 - Prob. 13.37APCh. 13 - Draw structures corresponding to the following...Ch. 13 - Draw structures corresponding to the following...Ch. 13 - Seven alkynes have the formula C6H10. Draw them,...Ch. 13 - Prob. 13.41APCh. 13 - Prob. 13.42APCh. 13 - There are four different pentenes having the...Ch. 13 - Prob. 13.44APCh. 13 - Prob. 13.45APCh. 13 - Draw line structures for the following alkenes....Ch. 13 - Which compound(s) in Problem 13.43 can exist as...Ch. 13 - Prob. 13.48APCh. 13 - Prob. 13.49APCh. 13 - Which of the following pairs are isomers, and...Ch. 13 - Prob. 13.51APCh. 13 - Prob. 13.52APCh. 13 - Prob. 13.53APCh. 13 - Prob. 13.54APCh. 13 - Prob. 13.55APCh. 13 - Prob. 13.56APCh. 13 - Prob. 13.57APCh. 13 - Prob. 13.58APCh. 13 - Prob. 13.59APCh. 13 - What alkene could you use to make the following...Ch. 13 - Prob. 13.61APCh. 13 - Prob. 13.62APCh. 13 - Prob. 13.63APCh. 13 - Prob. 13.64APCh. 13 - For each of the following reagents, decide whether...Ch. 13 - Prob. 13.66APCh. 13 - Prob. 13.67APCh. 13 - Prob. 13.68APCh. 13 - Salicylic acid (o-hydroxybenzoic acid) is used as...Ch. 13 - The following names are incorrect by IUPAC rules....Ch. 13 - Prob. 13.71CPCh. 13 - Prob. 13.72CPCh. 13 - Prob. 13.73CPCh. 13 - Prob. 13.74CPCh. 13 - Menthene, a compound found in mint plants, has the...Ch. 13 - Prob. 13.76CPCh. 13 - Prob. 13.77CPCh. 13 - Two products are possible when 2-pentene is...Ch. 13 - Ocimene, a compound isolated from the herb basil,...Ch. 13 - Describe how you could prepare the following...Ch. 13 - Which of the following compounds are capable of...Ch. 13 - Prob. 13.82GPCh. 13 - Superglue is an alkene polymer made from the...Ch. 13 - Draw all possible C5H10 alkene isomers having a...
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