Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 7, Problem 7.46SP
(a)
Interpretation Introduction
To determine: The direction of the dipole moment for the given
Interpretation: The direction of the dipole moment for the given alkenes is to be drawn and the compound that has the largest dipole moment in the given pair is to be stated.
Concept introduction: The polarity of an individual bond is measured as its bond dipole moment. A quantity that describes two opposite charges separated by a distance is called dipole moment. The dipole moment is calculated by the formula,
(b)
Interpretation Introduction
To determine: The direction of the dipole moment for the given alkenes and the compound that has the largest dipole moment in the given pair.
Interpretation: The direction of the dipole moment for the given alkenes is to be drawn and the compound that has the largest dipole moment in the given pair is to be stated.
Concept introduction: The polarity of an individual bond is measured as its bond dipole moment. A quantity that describes two opposite charges separated by a distance is called dipole moment. The dipole moment is calculated by the formula,
(c)
Interpretation Introduction
To determine: The direction of the dipole moment for the given alkenes and the compound that has the largest dipole moment in the given pair.
Interpretation: The direction of the dipole moment for the given alkenes is to be drawn and the compound that has the largest dipole moment in the given pair is to be stated.
Concept introduction: The polarity of an individual bond is measured as its bond dipole moment. A quantity that describes two opposite charges separated by a distance is called dipole moment. The dipole moment is calculated by the formula,
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CH2
H3C
H3C
COOH
Reagents
e. PB13
f. NaCN then H3O*
g. NBS, CCI4
h. CrO3, H2SO4
а.
HBr
b. Mg, ether
c. CO2, ether then H3O*
d. BH3, THF then H2O2, OH"
1. Write the IUPAC name of the following
а.
CH3-CH-O-CH2-CH3
CH3
b. CНЗ-СH-CH2-SH
CH3
c. CH3-CH-CH-CH2-CHO
| |
Cl
Br
d. CH3-CH2-C-CH2-CH-CH3
Cl
е.
CH3 -CH -C-CH3
СНЗ О
2. Write the structure of the following:
a. 2-Butanone
b. a-Hydroxybutyraldehyde
c. 2,3-Butanedione
d. 2-Methylpentanal
e. 4,4-Dimethyl-2pentanone
Give the structure corresponding to each name.a. 3-chloro-2-methylhexaneb. 4-ethyl-5-iodo-2,2-dimethyloctanec. cis-1,3-dichlorocyclopentaned. 1,1,3-tribromocyclohexanee. sec-butyl bromidef. 6-ethyl-3-iodo-3,5-dimethylnonane
Chapter 7 Solutions
Organic Chemistry (9th Edition)
Ch. 7.3A - Prob. 7.1PCh. 7.3A - Prob. 7.2PCh. 7.3B - Draw five more compounds of formula C4H6NOC1.Ch. 7.3B - For each of the following molecular formulas,...Ch. 7.4 - Give the systematic (IUPAC) names of the following...Ch. 7.5B - The following names are all incorrect. Draw the...Ch. 7.5B - Prob. 7.8PCh. 7.5B - a. How many stereogcmc double bonds are in...Ch. 7.6 - Teflon-coated frying pans routinely endure...Ch. 7.7B - Prob. 7.11P
Ch. 7.8B - Use the data in Table7-2 to predict the energy...Ch. 7.8C - Prob. 7.13PCh. 7.8E - Explain why each of the following alkenes is...Ch. 7.8F - Prob. 7.15PCh. 7.10 - Prob. 7.16PCh. 7.10A - SN1 substitution and E1 elimination frequently...Ch. 7.10C - Prob. 7.18PCh. 7.10C - Prob. 7.19PCh. 7.10C - Prob. 7.20PCh. 7.11 - Prob. 7.21PCh. 7.11 - Prob. 7.22PCh. 7.12 - Prob. 7.23PCh. 7.12 - Prob. 7.24PCh. 7.13 - Prob. 7.25PCh. 7.14B - Prob. 7.26PCh. 7.14B - Make models of the blowing compounds, and predict...Ch. 7.15 - Prob. 7.28PCh. 7.15 - Prob. 7.29PCh. 7.15 - Prob. 7.30PCh. 7.15 - Prob. 7.31PCh. 7.16 - Predict the major and minor elimination products...Ch. 7.17B - Predict the products and mechanisms of the...Ch. 7.18 - Propose mechanisms for the following reactions.Ch. 7.18 - Prob. 7.35PCh. 7.19B - The dehydrogenation of butane to trans-but-2-ene...Ch. 7.19B - Prob. 7.37PCh. 7.19B - Prob. 7.38PCh. 7.19B - Prob. 7.39PCh. 7 - Prob. 7.40SPCh. 7 - Prob. 7.41SPCh. 7 - Prob. 7.42SPCh. 7 - Prob. 7.43SPCh. 7 - Prob. 7.44SPCh. 7 - Prob. 7.45SPCh. 7 - Prob. 7.46SPCh. 7 - The energy difference between cis- and...Ch. 7 - Prob. 7.48SPCh. 7 - Prob. 7.49SPCh. 7 - Prob. 7.50SPCh. 7 - What halides would undergo E2 dehydrohalogenation...Ch. 7 - Prob. 7.52SPCh. 7 - Prob. 7.53SPCh. 7 - Write a balanced equation for each reaction,...Ch. 7 - Prob. 7.55SPCh. 7 - Using cyclohexane as your starting material, show...Ch. 7 - Show how you would prepare cyclopentene from each...Ch. 7 - Prob. 7.58SPCh. 7 - E1 eliminations of alkyl halides are rarely useful...Ch. 7 - Prob. 7.60SPCh. 7 - Propose mechanisms for the following reactions....Ch. 7 - Prob. 7.62SPCh. 7 - Prob. 7.63SPCh. 7 - Prob. 7.64SPCh. 7 - Prob. 7.65SPCh. 7 - Prob. 7.66SPCh. 7 - Prob. 7.67SPCh. 7 - Prob. 7.68SPCh. 7 - Prob. 7.69SPCh. 7 - Explain the dramatic difference in rotational...Ch. 7 - One of the following dichloronorbornanes undergoes...Ch. 7 - A graduate student wanted to make...Ch. 7 - Prob. 7.73SPCh. 7 - Prob. 7.74SPCh. 7 - Prob. 7.75SPCh. 7 - Prob. 7.76SP
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