Concept explainers
(a)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(b)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(c)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(d)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(e)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(f)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(g)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(i)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
(i)
To determine: The structure of the compound if it shows the geometric isomerism.
Interpretation: The structure of the compound if it shows the geometric isomerism is to be represented.
Concept introduction: The geometric isomerism is shown by an organic compound. The compounds that have two higher priority groups are on the same side of the double bond are represented by Z and the compounds that have two higher priority groups on the different side of the double bond are represented by
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Chapter 7 Solutions
Organic Chemistry (9th Edition)
- A student was given the structural formulas of several compounds and was asked to give them systematic names. How many did the student name correctly? Correct those that are misnamed. a. 4-bromo-3-pentanol b. 2,2-dimethyl-4-ethylheptane c. 5-methylcyclohexanol d. 1,1-dimethyl-2-cyclohexanol e. 5-(2,2-dimethylethyl)nonane f. isopentylbromide g. 3,3-dichlorooctane h. 5-ethyl-2-methylhexane i. 1-bromo-4-pentanol j. 3-isopropyloctane k. 2-methyl-2-isopropylheptane l. 2-methyl-N,N-dimethyl-4-hexanaminearrow_forwardDraw the structure of the following alkenes. Some of these compounds can show isomerism, and some cannot. Indicate which among these can show cis and trans isomers. a. 3-ethylhexa-2,4-diene b. pent-1,3-diene c. 3,7-dichloroocta-2,5-dienearrow_forwardDraw the structure of the following compounds. a. 1-ethyl-3-methylcycloheptane b. Cyclopropylcyclopentane c. 1,1-diethyl-4-(3,3-dimethylbutyl)cyclohexanearrow_forward
- Draw structures for the following molecules.a. 2-chlorobutane c. 1,1,1-trichloroethaneb. 1,3-difluorohexane d. 4-bromo-1-chlorobenzenearrow_forwardDetermine whether geometric isomers exist, draw the structures for cis and trans isomers for the following compounds. a.) hexa-1,3-diene b.)hepta-2,4-dienearrow_forwardName one structural isomer created by changing theposition of one or more halogen atoms in each alkylhalide.a. 2-chloropentane c. 1,3-dibromocyclopentaneb. 1,1-difluropropane d. 1-bromo-2-chloroethanearrow_forward
- 4. MAINIDEA Compare and contrast alkyl halides and aryl halides. 5. Draw structures for the following molecules. a. 2-chlorobutane c. 1,1,1-trichloroethane b. 1,3-difluorohexane d. 1-bromo-4-chlorobenzene 6. Define functional group and name the group present in each of the following structures. Name the type of organic compound each substance represents. a. CH3CH,CH2OH b. CH;CH,F c. CH;CH,NH2 7. Evaluate How would you expect the boiling points of propane and 1-chloropropane to compare? Explain your answer. d. CH3C- OH 8. Interpret Scientific Illustrations Examine the pair of substituted hydrocarbons illustrated at right, and decide whether it represents a pair of optical isomers. Explain your answer.arrow_forwardC. Write the condensed structural formula for each of the following molecules 1. 3-ethylhexane 2. 1,3-dimethylcyclopentane 3. 1,3-dichloro-3-methylheptane 4. Isopropylcyclopentane 5. 2-bromo-4-methylheptane D. Write the structural formula of the monohalogenated product formed in this reaction. CH –CH + Br tEh 3 3arrow_forwardXIII. Draw skeletal structures corresponding to the following names. a. 1-chloro-2-isopropylcyclopentane b. 3,5-dicyclohexylnonane c. 3,3-Diethyl-2,5-dimethylnonane d. 4-Isopropyl-3-methylheptanearrow_forward
- Which of the following names are correct and which areincorrect? If incorrect, write the correct name.a. 2,3-Dibromocyclobutane c. 1,2-Dimethylcyclopropaneb. 1,4-Diethylcyclobutane d. 4,5,6-Trichlorocyclohexanearrow_forwardDraw the structures for the following haloalkanes.a. 3-bromo-2-methylpentane b. 1-fluoro-3-methylcyclohexanearrow_forwardWhat is the product ? A. 3-methylhexane B. cis-sec-butene C. cis-3-methyl-2-hexene D. trans-ethyl-2-pentenearrow_forward